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http://dx.doi.org/10.5012/bkcs.2013.34.1.221

Preparation of Ruthenium Incorporated Heterogeneous Catalysts Using Hydroxyapatite as Catalytic Supports for Aerobic Oxidation of Alcohols  

Kim, Sohee (Department of Chemistry and RINS, Gyeongsang National University)
Jung, Jong-Hwa (Department of Chemistry and RINS, Gyeongsang National University)
Kim, Dong-Hee (Department of Orthopaedic Surgery, School of Medicine, Gyeongsang National University Hospital)
Woo, Dong Kyun (College of Pharmacy and Research Institute of Pharmaceutical Sciences, Gyeongsang National University)
Park, Joon B. (Institute of Fusion Science, Department of Chemistry Education, Chonbuk National University)
Choi, Myong Yong (Department of Chemistry and RINS, Gyeongsang National University)
Kwon, Ki-Young (Department of Chemistry and RINS, Gyeongsang National University)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.1, 2013 , pp. 221-224 More about this Journal
Abstract
Three different kinds of hydroxyapatites (HAPs) having different sizes and compositions are prepared by hydrothermal and molten salt syntheses. Using the ion exchange reactions, ruthenium ions are incorporated on the surface of HAPs. The crystallinity, morphology and ruthenium contents are investigated by XRD, SEM, TEM and ICP. We found that smaller size of HAP having large amounts of ruthenium under ion exchange reaction shows higher catalytic activity for aerobic oxidation of alcohols.
Keywords
Aerobic oxidation; Heterogeneous catalysts; Hydroxyapatite; Surface;
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