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http://dx.doi.org/10.5012/bkcs.2013.34.11.3410

Rapid and Ecofriendly Esterification of Alcohols with 2-Acylpyridazinones  

Kim, Bo Ram (Department of Chemistry & Research Institute of Natural Science, Gyeongsang National University)
Sung, Gi Hyeon (Department of Chemistry & Research Institute of Natural Science, Gyeongsang National University)
Ryu, Ki Eun (Department of Chemistry & Research Institute of Natural Science, Gyeongsang National University)
Kim, Jeum-Jong (Advanced Solar Technology Research Department, ETRI)
Yoon, Yong-Jin (Department of Chemistry & Research Institute of Natural Science, Gyeongsang National University)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.11, 2013 , pp. 3410-3414 More about this Journal
Abstract
Atom-economical esterification is of great importance in green chemistry. In this work, we demonstrated the catalyst and additive free esterification of alcohols by their reaction with 2-acyl-4,5-dichloropyridazin-3(2H)-ones without solvent at $100^{\circ}C$. Aliphatic and aromatic alcohols were converted into the corresponding esters in good to excellent yields. It is noteworthy that the reaction is solvent-free, atom-economic, easy-workup, and rapid and that the process is inexpensive.
Keywords
Esterification; 2-Acylpyridazin-3(2H)-one; Atom-economical reaction; Green chemistry; Heterocycles;
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Times Cited By KSCI : 2  (Citation Analysis)
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