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http://dx.doi.org/10.5012/bkcs.2012.33.7.2145

Colorimetric and Fluorescent Recognition of Fluoride by a Binaphthol Thioureido Derivative  

Tang, Lijun (Department of Chemistry, Liaoning Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University)
Wang, Nannan (Department of Chemistry, Liaoning Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University)
Guo, Jiaojiao (Department of Chemistry, Liaoning Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University)
Publication Information
Abstract
A new thiourea based receptor (1) was synthesized and applied to fluoride ion recognition in acetonitrile solution. Receptor 1 displayed dual changes in absorption and fluorescence emission intensities selectively for fluoride ions. The interaction of 1 with fluoride undergoes a deprotonation process that is confirmed by $^1H$ NMR titration.
Keywords
Chemosensor; Thiourea; Fluoride; Colorimetric; Fluorescence;
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