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http://dx.doi.org/10.5012/bkcs.2012.33.6.2017

Novel Lanthanide Coordination Polymers Prepared by Microwave Heating: [Ln(L)3(H2O)2](H2O)3 (Ln = Eu, Tb, Gd; L = trans-(3-py)-CH=CH-COO)  

Han, Sun-Hwa (Department of Chemistry (BK21), Sungkyunkwan University, Natural Science Campus)
Zheng, Zhen Nu (Department of Chemistry (BK21), Sungkyunkwan University, Natural Science Campus)
Cho, Sung-Il (Department of Chemical Engineering, University of Seoul)
Lee, Soon-W. (Department of Chemistry (BK21), Sungkyunkwan University, Natural Science Campus)
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.6, 2012 , pp. 2017-2022 More about this Journal
Abstract
Three isostructural lanthanide coordination polymers, $[Ln(L)_3(H_2O)_2](H_2O)_3$ {Ln = Eu (1), Tb (2), Gd (3); L = $trans$-3-(3-pyridyl)acrylate, (3-py)-CH=CH-COO}, were prepared from HL, lanthanide nitrate, and NaOH in $H_2O$ by microwave heating. In all coordination polymers, the metal is bonded to eight oxygen atoms, and all pyridyl nitrogen atoms do not coordinate to the metals. All polymers have a 1-D loop-connected chain structure. The hydrogen atoms in the aqua ligands and lattice water molecules all participate in the hydrogen bonds of the O-$H{\cdots}O$ or O-$H{\cdots}N$ type. The hydrogen bonds connect the 1-D chains to create a 2-D network. Polymer 1 exhibited red luminescence in the solid state at room temperature.
Keywords
Lanthanide coordination polymers; Crystal structure; Microwave heating; Luminescence;
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