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http://dx.doi.org/10.5012/bkcs.2012.33.5.1465

Electrochemical Thinning for Anodic Aluminum Oxide and Anodic Titanium Oxide  

Lee, In-Hae (Department of Chemical Engineering, Inha University)
Jo, Yun-Kyoung (Department of Chemical Engineering, Inha University)
Kim, Yong-Tae (Department of Chemical Engineering, Inha University)
Tak, Yong-Sug (Department of Chemical Engineering, Inha University)
Choi, Jin-Sub (Department of Chemical Engineering, Inha University)
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.5, 2012 , pp. 1465-1469 More about this Journal
Abstract
For given electrolytes, different behaviors of anodic aluminum oxide (AAO) and anodic titanium oxide (ATO) during electrochemical thinning are explained by ionic and electronic current modes. Branched structures are unavoidably created in AAO since the switch of ionic to electronic current is slow, whereas the barrier oxide in ATO is thinned without formation of the branched structures. In addition, pore opening can be possible in ATO if chemical etching is performed after the thinning process. The thinning was optimized for complete pore opening in ATO and potential-current behavior is interpreted in terms of ionic current-electronic current switching.
Keywords
Titanium oxide; Aluminum oxide; Anodization; Barrier oxide;
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