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http://dx.doi.org/10.5012/bkcs.2012.33.4.1317

Preparation of Self-Assembled Crystalline Microparticles with Bispyridyl Zn-Porphyrin  

Lee, Da-Hee (Department of Chemistry, Research Institute for Natural Sciences, Korea University)
Lee, Suk-Joong (Department of Chemistry, Research Institute for Natural Sciences, Korea University)
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.4, 2012 , pp. 1317-1320 More about this Journal
Abstract
Well-defined solid-state microcrystalline structures from bispyridyl Zn-porphyrin have been successfully synthesized. The coordinative interactions between pyridine and Zn are main responsible for this translation of porphyrin molecular building blocks to crystalline microscopic objects. The hexagonal plates are obtained from acetonitrile and rhombus plates are grown from toluene solution. With a simple manipulation during the microcrystal growth, such as growth temperature and time, the morphologies can be controlled by adopting different molecular packing. Consequently, morphologies of microcrystals have been diversified.
Keywords
Porphyrin; Building block; Pyridine; Crystalline; Morphology;
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