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http://dx.doi.org/10.5012/bkcs.2012.33.4.1264

Rational Design of Coordination Polymers with Flexible Oxyethylene Side Chains  

Choi, Eun-Young (Department of Molecular Science and Technology, Ajou University)
Gao, Chun-Ji (Department of Molecular Science and Technology, Ajou University)
Lee, Suck-Hyun (Department of Molecular Science and Technology, Ajou University)
Kwon, O-Pil (Department of Molecular Science and Technology, Ajou University)
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.4, 2012 , pp. 1264-1267 More about this Journal
Abstract
We rationally designed and synthesized metallopolymers with organic 1,4-benzenedicarboxylic acid (BDC) linkers with different lengths of oxyethylene side chains in order to examine the influence of side chains on the coordination characteristics. While in a previous report the BDC linkers with alkyl side chains were found to form three-dimensional (3D) isoreticular metal-organic framework (IRMOF) structures or one-dimensional (1D) coordination polymeric structures with short $-O(CH_2)_6CH_3$ or long $-O(CH_2)_9CH_3$ side chains, respectively, new BDC linkers with oxyethylene side chains of the same lengths, $-(OCH_2CH_2)_2CH_3$ and $-(OCH_2CH_2)_3CH_3$, form only 3D IRMOF structures. This result is attributed to the higher flexibility and smaller volume of oxyethylene side chains compared to alkyl side chains.
Keywords
Metallopolymers; Metal-organic framework; Coordination polymers;
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