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http://dx.doi.org/10.5012/bkcs.2012.33.4.1247

Nano Structured Potentiometric Sensors Based on Polyaniline Conducting Polymer for Determination of Cr (VI)  

Ali, Mohammad-Khah (Chemistry Department, Faculty of Science, University of Guilan)
Ansari, Reza (Chemistry Department, Faculty of Science, University of Guilan)
Delavar, Ali Fallah (Chemistry Department, Faculty of Science, University of Guilan)
Mosayebzadeh, Zahra (Chemistry Department, Faculty of Science, University of Guilan)
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.4, 2012 , pp. 1247-1252 More about this Journal
Abstract
In this paper, a potentiometric sensor based on polyaniline conducting polymer for potentiometric determination of Cr (VI) ions is reported. Polyaniline was synthesized electrochemically (cyclic voltammetry method) onto a micro pencil graphite electrode (0.7 mm diameter) in the presence of HCl and diphenylcarbazide (termed as (PGE/PAni/DPC). Some initial experiments were performed in order to find out the optimized conditions for preparation of the introduced Cr (VI) sensor electrode. The plot of E vs. log [Cr (VI)], showed a linear response in the range from $1.0{\times}10^{-6}$ to $1.0{\times}10^{-1}$ M. High repeatability with the detection limit of $8.0{\times}10^{-7}$ M was obtained.
Keywords
Chromium (VI); Potentiometric sensor; Polyaniline; Diphenylcarbazide;
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Times Cited By SCOPUS : 4
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1 Gomez, V.; Callao, M. P. Trends. Anal. Chem. 2006, 25, 1006.   DOI   ScienceOn
2 Singh, A. K.; Gupta, V. K.; Gupta, B. Anal. Chim. Acta 2007, 585, 171.
3 Kortenkamp, A.; Casadevall, M.; Faux, S. P.; Jenner, A.; Shayer, R. O. J.; Woodbridge, N.; O'Brien, P. Arch. Biochem. Biophys. 1996, 329, 199.   DOI   ScienceOn
4 National Toxicology Program, Chromium Hexavalent Compounds; Ninth Report on Carcinogens, NTP, Department of Health and Human Services, 2000.
5 De Paoli, M. A.; Gazotti, W. A. J. Braz. Chem. Soc. 2002, 13, 410.
6 Korostynska, O.; Arshak, K.; Gill, E.; Arshak, A. Sensors 2007, 7, 3027.   DOI
7 Basavaraja, C.; Kim, N. R.; Jo, E. A.; Pierson, R.; Huh, D. S.; Venkataraman, A. Bull. Korean Chem. Soc. 2009, 30(11), 2701.   DOI
8 Del Valle, M. A.; Diaaz, F. R.; Bodini, M. E.; Pizarro, T.; Cordova, R.; Gomez, H.; Schrebler, R. J. Appl. Electrochem. 1998, 28, 943.   DOI   ScienceOn
9 Lindfors, T.; Ivaska, A. Anal. Chim. Acta 2001, 437, 171.   DOI   ScienceOn
10 Zhang, X.; Manohar, S. K. Chem. Commun. 2004, 20, 2360.
11 Zhang, L.; Zhang, L.; Wan, M.; Wei, Y. Synth. Met. 2006, 156, 454.   DOI   ScienceOn
12 Qiu, H. J.; Wan, M. X.; Matthews, B.; Dai, L. M. Macromol. 2001, 34, 675.   DOI   ScienceOn
13 Huang, J. Pure. Appl. Chem. 2006, 78(1), 15.   DOI
14 Willes, G. J.; Blaton, N. M.; Peeters, O. M.; Deranter, C. J. Anal. Chim. Acta 1977, 88, 345.   DOI   ScienceOn
15 Naoi, K.; Lien, M.; Smyrl, W. H. J. Electrochem. Soc. 1991, 138, 440.   DOI
16 Chiang, J. C.; MacDiarmid, A. G. Synth. Metals 1989, 13, 193.
17 Wang, Y.; Tran, H. D.; Kaner, R. B. Macromo. Rapid. Commun. 2011, 32, 35.   DOI   ScienceOn
18 Sanchez-Moreno, R. A.; Gismera, M. J.; Teresa Sevilla, M.; Procopio, J. R. Sens. & Actuators B 2010, 143, 716.   DOI   ScienceOn
19 Bakker, E.; Buhlmann, P.; Pretsch, E. Chem. Rev. 1997, 97, 3083.   DOI   ScienceOn
20 Guertin, J.; Jacobs, J. A.; Avakian, C. P. Chromium (VI) Handbook, Written by Independent Environmental Technical Evaluation Group (IETEG); CRC press: 2005.
21 Guell, R.; Fontas, C.; Salvado, V.; Antico, E. Anal. Chim. Acta 2007, 594, 162.   DOI   ScienceOn
22 Katz, S. A.; Salem, H. The Biological and Environmental Chemistry of Chromium; VCH: New York, USA, 1994.
23 Koryta, J.; Stulik, K. Ion Selective Electrodes; Cambridge University Press: Cambridge, 1983.
24 Hassan, S. S. M.; Abbas, M. N.; Moustafa, G. E. A. Talanta 1996, 43, 797.   DOI   ScienceOn
25 Hassan, S. S. M.; El-Shahawi, M. S.; Othman, A. M.; Mosaad, M. A. Anal. Sci. 2005, 21, 673.   DOI   ScienceOn
26 Ardakani, M. M.; Dastanpour, A.; Salavati-Niasari, M. Microchim. Acta 2005, 150, 67.   DOI
27 Choi, W. Y.; Minoura, N.; Moon, S. H. Talanta 2005, 66, 1254.   DOI   ScienceOn
28 Singh, L. P.; Bhatnagar, J. M.; Tanaka, S.; Tsue, H.; Mori, M. Anal. Chim. Acta 2005, 546, 199.   DOI   ScienceOn
29 Erturun, H. E. K.; Yilmaz, M.; Kilic, E. Sens. Actuators B 2007, 127, 497.   DOI   ScienceOn
30 Choi, Y. W.; Moon, S. H. Environ. Monit. Asses 2001, 70, 167.   DOI   ScienceOn
31 Choi, Y. W.; Moon, S. H. Environ. Monit. Asses 2004, 92, 163.   DOI
32 Luthra, V.; Singh, R.; Gupta, S. K.; Mansingh, A. Curr. Appl. Phys. 2003, 3, 219.   DOI   ScienceOn
33 Kim, Y.; Kim, J. S.; Thieu, M. T.; Dinh, H. C.; Yeo, I. H.; Cho, W. I.; Mho, S. I. Bull. Korean Chem. Soc. 2010, 31(11), 3109.   DOI
34 Iqbal, P.; Critchle, K.; Begum, S.; Attwoo, D.; Evan, S. D.; Jone, I. P.; Preec, J. A. J. Exper. Nanosci. 2006, 1(2), 143.   DOI   ScienceOn
35 Ansari, R.; Fallah Delavar, A.; Aliakbar, A.; Mohammad-khah, A. J. Solid. State. Electrochem. 2011, 16(3), 869.
36 Ansari, R.; Fallah Delavar, A. J. Appl. Polym. Sci. 2009, 113, 2293.   DOI   ScienceOn