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http://dx.doi.org/10.5012/bkcs.2012.33.4.1225

A New Unsymmetrical Zinc Phthalocyanine as Photosensitizers for Dye-sensitized Solar Cells  

Zhang, Dan (Department of Chemistry, College of Science, North University of China)
Zhang, Xue-Jun (Department of Chemistry, College of Science, North University of China)
Zhang, Lei (Department of Chemistry, College of Science, North University of China)
Mao, Li-Jun (Department of Chemistry, College of Science, North University of China)
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.4, 2012 , pp. 1225-1230 More about this Journal
Abstract
A new unsymmetrical zinc phthalocyanine has been designed and synthesized based on the 'push-pull' and extended ${\pi}$-conjugation concept for the dye-sensitized solar cells. Three tert-butoxy groups, which act as electron releasing ('push'), enhance the solubility of phthalocyanine in common organic solvents and reduce the aggregation. Hydroxy substituted 9,10-anthraquinones act as electron acceptors ('pull') for the study of photoinduced electron transfer processes as well as grafting onto nanocrystalline $TiO_2$. The new unsymmetrical zinc phthalocyanine was fully characterized by FTIR, UV-vis, $^1H$ NMR, cyclic voltammetry and differential pulse voltammetry. The new sensitizer was tested in dye-sensitized solar cells, and gave a better performance.
Keywords
Phthalocyanine; Unsymmetrical; Dye-sensitized solar cells; Electrochemistry;
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