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http://dx.doi.org/10.5012/bkcs.2012.33.1.35

Metalloporphyrin-Catalyzed Chemoselective Oxidation of Sulfides with Polyvinylpyrrolidone-Supported Hydrogen Peroxide: Simple Catalytic System for Selective Oxidation of Sulfides to Sulfoxides  

Zakavi, Saeed (Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS))
Abasi, Azam (School of Chemistry, Damghan University)
Pourali, Ali Reza (School of Chemistry, Damghan University)
Talebzadeh, Sadegh (Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS))
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.1, 2012 , pp. 35-38 More about this Journal
Abstract
Room temperature oxidation of organic sulfides with polyvinylpyrrolidone-supported hydrogen peroxide (PVP-$H_2O_2$) in the presence of Mn(III) complexes of meso-tetraphenylporphyrin, Mn(TPP)X (X = OCN, SCN, OAc, Cl) and imidazole (ImH) leads to the highly chemoselective (ca. 90%) oxidation of sulfides to the corresponding sulfoxide. The efficiency of reaction has been shown to be influenced by different reaction parameters such as the nature of counterion (X) and solvent as well as the molar ratio of reactants. Using Mn(TPP)OCN and ImH in 1:15 molar ratio and acetone as the solvent leads to the efficient oxidation of different sulfides.
Keywords
Mn(III)-meso-tetraphenylporphyrin; PVP-$H_2O_2$; Oxidation of sulfides; Sulfoxide;
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