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http://dx.doi.org/10.5012/bkcs.2012.33.12.4131

Bulk Coordination Polymerization of Dicyclopentadiene (DCPD) by Pd Complexes Containing β-Ketoiminate or β-Diketiminate Ligands  

Lee, Eung Jun (Department of Chemistry, Inha University)
Kim, Ho Sup (Department of Chemistry, Inha University)
Lee, Byoung Ki (Department of Chemistry, Inha University)
Hwang, Woon Sung (R&D Center, Kolon Industries, Inc.)
Sung, Ik Kyoung (R&D Center, Kolon Industries, Inc.)
Lee, Ik Mo (Department of Chemistry, Inha University)
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.12, 2012 , pp. 4131-4136 More about this Journal
Abstract
Several palladium complexes containing ${\beta}$-ketoiminate and ${\beta}$-diketiminate ligands successfully produced poly(DCPD) possibly via vinyl addition. It was found that catalysts with ${\beta}$-diketiminate ligands containing bulkier aryl substituents showed the highest activity in the presence of MAO as a cocatalyst. Purity of DCPD is quite essential for the higher activity and small amount of organic solvent such as $CH_2Cl_2$ and toluene is required to reduce the viscosity of the reactant mixture for the higher activity. $^1H$ NMR spectra of produced polymers with N,N-dimethylanilinium tetra(pentafluorophenyl)borate (N,N-DAPFAr"$_4$) show that 5,6-double bond of DCPD is removed with 2,3-double bond remaining. Produced poly(DCPD) with MAO cocatalyst is quite rigid and insoluble in common organic solvents but rather brittle.
Keywords
Palladium complexes; ${\beta}$-Ketoiminate; ${\beta}$-Diketiminate; Vinyl addition polymerization; Poly(DCPD);
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1 US patent 4436858, 1984.
2 US patent 4002815, 1977.
3 US patent 4458037 1984.
4 US patent 4507453, 1985.
5 US patent 2003/0144437 A1, 2003.
6 US patent 2003/0083445 A1, 2003.
7 Scholl, M.; Ding, S.; Lee, C. W.; Grubbs, R. H. Org. Lett. 1999, 1, 953.   DOI   ScienceOn
8 Dorta, R.; Kelly, R. A., III; Nolan, S. P. Adv. Synth. Catal. 2004, 346, 917.   DOI   ScienceOn
9 Davidson, T. A.; Wagener, K. B.; Priddy, D. B. Macromolecules 1996, 29, 786.   DOI   ScienceOn
10 Davidson, T. A.; Wagener, K. B. J. Mol. Catal. A: Chem. 1998, 133, 67.   DOI   ScienceOn
11 Lee, D. H.; Hwang, Y. J.; Yoon, J. S.; Choi, M. K.; Lee, I. M. Bull. Korean Chem. Soc. 2009, 30, 636.   DOI   ScienceOn
12 Parks, J. E.; Holm, R. H. Inorg. Chem. 1968, 7, 1408.   DOI
13 Tang, L. M.; Duan, Y. Q.; Li, X. F.; Li, Y. S. J. Organomet. Chem. 2006, 691, 2023.   DOI   ScienceOn
14 Budzelaar, P. H. M.; Moonen, N. N. P.; de Gelder, R.; Smits, J. M. M.; Gal, A. W. Eur. J. Inorg. Chem. 2000, 753.
15 Feldman, J.; McLain, S. J.; Parthasarathy, A.; Marshall, W. J.; Calabrese, J. C.; Arthur, S. D. Organometallics 1997, 16, 1514.   DOI   ScienceOn
16 Ladipo, F. T.; Anderson, G. K. Organometallics 1994, 13, 303.   DOI   ScienceOn
17 Brookhart, M.; Grant, B.; Volpe, A. F., Jr. Organometallics 1992, 11, 3920.   DOI
18 Blank, F.; Vieth, J. K.; Ruiz, J.; Rodriguez, V.; Janiak, C. J. Organomet. Chem. 2011, 696, 473.   DOI   ScienceOn
19 Rahim, M.; Taylor, N. J.; Xin, S.; Collins, S. Organometallics 1998, 17, 1315.   DOI   ScienceOn
20 Tian, X.; Goddard, R.; Põrschke, K.-R. Organometallics 2006, 25, 5854.   DOI   ScienceOn
21 Na, S. J.; Wu, C. J.; Yoo, J.; Kim, B. E.; Lee, B. Y. Macromolecules 2008, 41, 4055.   DOI   ScienceOn