Browse > Article
http://dx.doi.org/10.5012/bkcs.2012.33.12.4069

Synthesis, Structures, and Catalytic Properties of Ionic Metallacyclodimeric Palladium(II) Complexes  

Kim, Sung Min (Department of Chemistry, Pusan National University)
Park, Kyung Hwan (Department of Chemistry, Pusan National University)
Lee, Haeri (Department of Chemistry, Pusan National University)
Moon, So Yun (Department of Chemistry, Pusan National University)
Jung, Ok-Sang (Department of Chemistry, Pusan National University)
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.12, 2012 , pp. 4069-4073 More about this Journal
Abstract
Metallacyclodimeric complexes of $[(Me_4en)Pd(L)]_2(ClO_4)_4$ ($Me_4en$ = N,N,N',N'-tetramethylethylenediamine; L = dimethylbis(4-pyridyl)silane (dmps), methylvinylbis(4-pyridyl)silane (mvps)) have been synthesized, and their structures have been characterized by X-ray single crystallography. The skeletal structures consist of one 20-membered metallamacrocycle, two 5-membered metallacycles, and four pyridyl groups. The local geometry around the palladium(II) ion approximates to a typical square planar arrangement with four nitrogen donors. Delicate difference in catalytic effects on hydrogenation was investigated based on the structure of catalyst and substrates.
Keywords
Dimethylbis(4-pyridyl)silane; Hydrogenation catalysis; Metallacyclodimer; Methylvinylbis(4-pyridyl)silane; Palladium(II) complexes;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Swiegers, G. F.; Malefetse, T. J. Coord. Chem. Rev. 2002, 225, 91.   DOI   ScienceOn
2 Cotton, F. A.; Lin, C.; Murillo, C. A. Acc. Chem. Res. 2001, 34, 759.   DOI   ScienceOn
3 Leinigner, S.; Olenyuk, B.; Stang, P. J. Chem. Rev. 2000, 100, 853.   DOI   ScienceOn
4 Jude, H.; Disteldorf, H.; Fischer, S.; Wedge, T.; Hawkridge, A. M.; Arif, A. M.; Hawthorne, M. F.; Muddiman, D. C.; Stang, P. J. J. Am. Chem. Soc. 2005, 127, 12131.   DOI   ScienceOn
5 Wang, P.; Moorefield, C. N.; Newkome, G. R. Angew. Chem., Int. Ed. 2005, 44, 1679.   DOI   ScienceOn
6 Grote, Z.; Scopelliti, R.; Severin, K. J. Am. Chem. Soc. 2004, 126, 16959.   DOI   ScienceOn
7 Benkstein, K. D.; Hupp, J. T.; Stern, C. L. J. Am. Chem. Soc. 1998, 120, 12982.   DOI   ScienceOn
8 Jung, O.-S.; Lee, Y.-A.; Kim, Y. J.; Hong, J. Cryst. Growth Des. 2002, 2, 497.   DOI   ScienceOn
9 Uehara, K.; Kasai, K.; Mizuno, N. Inorg. Chem. 2007, 46, 2563.   DOI   ScienceOn
10 Zhang, Z.; Cai, R.; Chen, Z.; Zhou, X. Inorg. Chem. 2007, 46, 321.   DOI   ScienceOn
11 Yao, Q.; Kinney, E. P.; Zheng, C. Org. Lett. 2004, 6, 2997.   DOI   ScienceOn
12 Fujita, M.; Ibukuro, F.; Hagihara, H.; Ogura, K. Nature 1994, 367, 720.   DOI   ScienceOn
13 Chun, I. S.; Lee, K. S.; Do, J.; Hong, Y.; Jung, O.-S. Chem. Lett. 2007, 36, 548.   DOI   ScienceOn
14 Chun, I. S.; Kwon, J. A.; Yoon, H. J.; Bae, M. N.; Hong, J.; Jung, O.-S. Angew. Chem., Int. Ed. 2007, 46, 4960.   DOI   ScienceOn
15 Seidel, S. R.; Stang, P. J. Acc. Chem. Res. 2002, 35, 972.   DOI   ScienceOn
16 Jung, O.-S.; Kim, Y. J.; Kim, K. M.; Lee, Y.-A. J. Am. Chem. Soc. 2002, 124, 7906.   DOI   ScienceOn
17 Jung, O.-S.; Lee, Y.-A.; Kim, Y. J. Chem. Lett. 2002, 31, 1906.
18 Jung, O.-S.; Kim, Y. J.; Lee, Y.-A.; Kang, S. W.; Choi, S. N. Cryst. Growth Des. 2004, 4, 23.   DOI   ScienceOn
19 Lee, J. W.; Kim, E. A.; Kim, Y. J.; Lee, Y.-A.; Pak, Y.; Jung, O.-S. Inorg. Chem. 2005, 44, 3151.   DOI   ScienceOn
20 Schmitz, M.; Leninger, S.; Fan, J.; Arif, A. M.; Stang, P. J. Organometallics 1999, 18, 4817.   DOI   ScienceOn
21 Phan, N. T. S.; Van der Sluys, M.; Jones, C. W. Adv. Synth. Catal. 2006, 348, 609.   DOI   ScienceOn
22 Wang, H.; Zhong, R.; Guo, X.-Q.; Feng, X.-Y.; Hou, X.-F. Eur. J. Inorg. Chem. 2010, 174.
23 Weng, Z.; Teo, S.; Koh, L. L.; Hor, T. S. A. Organometallics 2004, 23, 3603.   DOI   ScienceOn
24 Jain, V. K.; Jain, L. Coord. Chem. Rev. 2005, 249, 3075.   DOI   ScienceOn
25 Sheldrick, G. M.; SHELXS-97: A Program for Structure Determination, University of Gottingen, Germany (1997); G. M. Sheldrick, SHELXL-97: A Program for Structure Refinement, University of Gottingen, Germany (1997).
26 Ryu, Y. K.; Kim, C. W.; Noh, T. H.; Yoo, K. H.; Jung, O.-S. J. Coord. Chem. 2010, 63, 3888.   DOI   ScienceOn
27 Islam, S. M.; Mondal, P.; Tuhina, K.; Roy, A. S. J. Chem. Technol. Biotechnol. 2010, 85, 999.   DOI   ScienceOn
28 Evrard, D.; Groison, K.; Mugnier, Y.; Harvey, P. D. Inorg. Chem. 2004, 43, 790.   DOI   ScienceOn