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http://dx.doi.org/10.5012/bkcs.2012.33.12.4047

A New and Facile Protocol for the Synthesis of Dithiocarbamate-linked 3,4-Dihydro-2H-pyran Using N-Halo Catalysts Under Mild Conditions Reaction  

Ghorbani-Vaghei, Ramin (Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali-Sina University)
Amiri, Mostafa (Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali-Sina University)
Veisi, Hojat (Department of chemistry, Payame Noor University)
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.12, 2012 , pp. 4047-4051 More about this Journal
Abstract
A new and facile protocol for the synthesis of dithiocarabamate in EtOH/$H_2O$ is described. Reaction of aromatic and aliphatic amines with $CS_2$ and 3,4-dihydro-2H-pyran in the presence of N,N,N',N'-tetrabromobenzene-1,3-disulfonamide [TBBDA] and poly(N-bromo-N-ethylbenzene-1,3-disulfonamide) [PBBS] gives the corresponding dithiocarbamates in good to high yields.
Keywords
Dithiocarabamates; Amine; Carbon disulfide ($CS_2$); 3,4-Dihydro-2H-pyran (DHP); TBBDA; PBBS;
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