Browse > Article
http://dx.doi.org/10.5012/bkcs.2012.33.12.3987

Preparation of Highly Stabilized Silver Nanopowders by the Thermal Reduction and Their Properties  

Kim, Kyoung-Young (Department of Nanobiomedical Science & WCU Research Center, Dankook University Graduate School)
Gong, Myoung-Seon (Department of Nanobiomedical Science & WCU Research Center, Dankook University Graduate School)
Park, Chan-Kyo (Department of Applied Chemical Engineering, Dankook University)
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.12, 2012 , pp. 3987-3992 More about this Journal
Abstract
Silver nanopowders were prepared from silver 2-ethylhexylcarbamate (Ag-EHCB) complexes by simple thermal reduction at $85^{\circ}C$ without any reducing agent in organic solvent. 2-Ethylhexylammonium 2-ethylhexylcarbamate (EHAEHC) was investigated in terms of their abilities to stabilize the silver nanoparticles (Ag-NPs) and its subsequent effects on the preventing aggregation between Ag-NPs. Conditions (concentration of stabilizer and reaction time) used to reduce Ag-EHCB complex were systematically varied to determine their effects on the sizes of Ag-NPs. The formation of the stabilized Ag-NPs were easily monitored by UV-vis spectroscopy and characterized by TGA, TEM, SEM and XRD. When EHAEHC was used as a stabilizer, Ag-NPs of 10-30 nm in diameter were easily obtained in high yield. Silver patterns were obtained from a silver nano-paste by heat treatment at $200^{\circ}C$ in air and were found to have resistivity values of $2.9{\times}10^{-8}\;{\Omega}{\cdot}m$.
Keywords
Silver 2-ethylhexylcarbamate; Nanopowders; Thermal reduction; Silver nano-paste;
Citations & Related Records
Times Cited By KSCI : 8  (Citation Analysis)
연도 인용수 순위
1 Lee, P. C.; Meisel, D. J. Phys. Chem. 1982, 86, 3391.   DOI
2 Imahori, H.; Kashiwagi, Y.; Hanada, Y.; Endo, Y.; Nishimura, Y.; Yamazaki, I.; Fukuzumi, S. J. Mater. Chem. 2003, 13, 2890.   DOI   ScienceOn
3 Sun, Y.; Mayers, B.; Xia, Y. Nano Lett. 2003, 3, 675.   DOI   ScienceOn
4 Turkevich, J.; Stevenson, P. C.; Hiller, J. Discuss. Farasay Soc. 1951, 11, 55.   DOI
5 Sondi, I.; Goia, D. V.; Matijeviæ, E. J. Colloid Interface Sci. 2003, 260, 75.   DOI   ScienceOn
6 Evanoff, D. D., Jr.; Chumanov, G. J. Phys. Chem. B 2004, 108, 13948.   DOI   ScienceOn
7 Kats, H.; Bao, Z.; Gilat, S. Acc. Chem. Res. 2001, 34, 359.   DOI   ScienceOn
8 Dimitrakopoulos, C. D.; Malenfant, P. R. L. Adv. Mater. 2002, 14, 99.   DOI   ScienceOn
9 Ong, B. S.; Wu, Y.; Liu, P.; Gardner, S. J. Am. Chem. Soc. 2004, 126, 3378.   DOI   ScienceOn
10 Ong, B. S.; Wu, Y.; Liu, P.; Jiang, L.; Murti, K. Synth. Met. 2004, 142, 49.   DOI   ScienceOn
11 Li, Y.; Wu, Y.; Ong, B. S. J. Am. Chem. Soc. 2005, 127, 3266.   DOI   ScienceOn
12 Sirringhaus, H.; Tessler, N.; Friends, R. H. Science 1998, 280, 1741.   DOI   ScienceOn
13 Sirringhaus, H.; Kawasem, T.; Friend, R. H.; Shimoda, T.; Inbasekaran, M.; Wu, W.; Woo, E. P. Science 2000, 290, 2123.   DOI   ScienceOn
14 Lee, P. C.; Meisel, D. J. Phys. Chem. 1982, 86, 3391.   DOI
15 Nickel, U.; Castell, A.; Pöppl, K.; Shirtcliffe, N. Langmuir 2000,16, 9087.   DOI   ScienceOn
16 Sondi, L.; Matijevi , D. V. E. J. Colloid Interface Sci. 2003, 260, 75.   DOI   ScienceOn
17 Van Hyning, D. L.; Zukoski, C. F. Langmuir 1998, 14, 7034.   DOI   ScienceOn
18 Rodriguez-Gattorno, G.; Diaz, D.; Rendon, L.; Hernandes-Segura, G. O. J. Phys. Chem. B 1982, 106, 2482.
19 Dell'Amico, D. B.; Calderazzo, F.; Labella, L.; Marchetti, F.; Pampaloni, G. Chem. Rev. 2003, 103, 3857.   DOI   ScienceOn
20 Park, M. S.; Lim, T. H.; Jeon, Y. M.; Kim, J. G.; Joo, S. W.; Gong, M. S. J. Colloid Interface Sci. 2008, 321, 60.   DOI   ScienceOn
21 Abe, K.; Hanada, T.; Yoshida, Y.; Tanigaki, N.; Takiguchi, H.; Nagasawa, H.; Nakamoto, T.; Yamaguchi, K.; Yase, K. Thin Solid Films 1998, 524, 327.
22 Yamamoto, M.; Nakamoto, M. J. Mater. Chem. 2003, 13, 2064.   DOI   ScienceOn
23 Dearden, A. L.; Smith, P. J.; Shin, D. Y.; Reis, N.; Derby, B.; O'Brienl, P. Macromol. Rapid Commun. 2005, 26, 315.   DOI   ScienceOn
24 Grodzicki, A.; Lakomska, I.; Piszczek, P.; Szymanska, I.; Sz yk, E. Coordination Chem. Rev. 2005, 249, 2232.   DOI   ScienceOn
25 Liu, X.; Luc, S.; Zhang, J.; Cao, W.; Thermochim. Acta 2006, 440, 1.   DOI   ScienceOn
26 Kashiwagi, Y.; Yamamoto, M.; Nakamoto, M. J. Colloid Interface Sci. 2006, 300, 169.   DOI   ScienceOn
27 Hong, H. K.; Gong, M. S.; Park, C. K. Bull. Korean Chem. Soc. 2009, 30, 2669.   DOI   ScienceOn
28 Park, H. S.; Park, H. S.; Gong, M. S. Bull. Korean Chem. Soc. 2010, 31, 2575.   DOI   ScienceOn
29 Park, H. S.; Park, H. S.; Gong, M. S. Macromol. Res. 2010, 18, 897.   DOI   ScienceOn
30 Park, H. S.; Shin, U. S.; Kim, H. W.; Gong, M. S. Bull. Korean Chem. Soc. 2011, 32, 273.   DOI   ScienceOn
31 Hong, H. K.; Shin, U. S.; Kim, H. W.; Gong, M. S. Bull. Korean Chem. Soc. 2011, 32, 1583.   DOI   ScienceOn
32 Park, H. S.; Gong, M. S. Bull. Korean Chem. Soc. 2012, 33, 483.   DOI   ScienceOn
33 Alessio, R.; Dell'Amico, D. B.; Calderazzo, F.; Englert, U.; Guarini, A.; Labella, L.; Strasser, P. Helv. Chim. Acta 1998, 81, 219.   DOI   ScienceOn
34 Hong, H. K.; Park, C. K.; Gong, M. S. Bull. Korean Chem. Soc. 2010, 31, 1252.   DOI   ScienceOn
35 Park, H. S.; Park, H. S.; Gong, M. S. Polymer (Korea) 2010, 34, 144.
36 McGhee, W. D.; Riley, D.; Christ, K.; Pan, Y.; Parnas, B. J. Org. Chem. 1995, 60, 2820.   DOI   ScienceOn
37 Hampe, E. M.; Rudkevich, D. M. Tetrahedron 2003, 59, 9619.   DOI   ScienceOn