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http://dx.doi.org/10.5012/bkcs.2011.32.5.1692

Two d10 Metal Coordination Polymers Based on 1H-1,2,4-Triazole: Synthesis, Structure and Fluorescence  

Zhang, Xiu-Cheng (College of Science, Northeast Forestry University)
Xu, Ling (REQUIMTE & Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto)
Liu, Wen-Guang (College of Science, Northeast Forestry University)
Liu, Bing (REQUIMTE & Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto)
Publication Information
Bulletin of the Korean Chemical Society / v.32, no.5, 2011 , pp. 1692-1696 More about this Journal
Abstract
The reactions of 1H-1,2,4-triazole (Htr) with $MX_2$ ($ZnCl_2$ for 1; $CdBr_2$ for 2) resulted in two coordination polymers, [Zn(tr)Cl]$_n$ (1) and $[Cd(Htr)_2Br_2]_n$ (2). The structural analyses indicate that 1 and 2 feature a 2D layer and 1D triple chain, respectively. In 1, neighouring Zn atoms are connected by ${\mu}_3-1$ ${\kappa}N$: 2 ${\kappa}N$: $4{\kappa}N-tr^-$ anionic ligand into 6- and 16-membered rings, further grow into a 2D sheet. Cd atoms in 2 are bonded by two ${\mu}_2-Br^-$ bridges and neutral ${\mu}_2$-1 ${\kappa}N$: 2 ${\kappa}N$-Htr to form a 1D triple chain. The fluorescent characterizations of 1, 2 and the free Htr ligand feature simlilar emission peakes at 444, 446 and 423 nm respectively, which can be assigned to intra-ligand ${\pi}-{\pi}^*$ transition of (H)tr. The energy gaps of 5.90 eV for 1, 5.16 eV for 2, and 5.93 eV for Htr suggest that the compounds behave as insulators.
Keywords
Cadmium(II); Crystal structure; Fluorescence; 1,2,4-Triazole; Zinc(II);
Citations & Related Records
Times Cited By KSCI : 3  (Citation Analysis)
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