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http://dx.doi.org/10.5012/bkcs.2011.32.3.787

Brønsted Acidic Ionic Liquids as Efficient Catalysts for Clean Synthesis of Carbamatoalkyl Naphthols  

Tavakoli-Hoseini, Niloofar (Department of Chemistry, Faculty of Sciences, Mashhad Branch, Islamic Azad University)
Heravi, Majid M. (Department of Chemistry, School of Sciences, Alzahra University)
Bamoharram, Fatemeh F. (Department of Chemistry, Faculty of Sciences, Mashhad Branch, Islamic Azad University)
Davoodnia, Abolghasem (Department of Chemistry, Faculty of Sciences, Mashhad Branch, Islamic Azad University)
Publication Information
Bulletin of the Korean Chemical Society / v.32, no.3, 2011 , pp. 787-792 More about this Journal
Abstract
Under mild conditions and without any additional organic solvent, synthesis of carbamatoalkyl naphthols could be carried out in the present of two halogen-free Br${\phi}$nsted acidic ionic liquids, 3-methyl-1-(4-sulfonic acid)butylimidazolium hydrogen sulfate and N-(4-sulfonic acid)butylpyridinium hydrogen sulfate. A wide range of aromatic aldehydes easily undergo condensation with $\beta$-naphthol and methyl or benzyl carbamate to afford the desired products of good purity in excellent yields. The present methodology offers several advantages such as a simple procedure with an easy work-up, short reaction times, and excellent yields. The catalysts could be recycled and reused for several times without substantial reduction in their catalytic activities.
Keywords
Br${\phi}$nsted-acidic ionic liquids; Carbamatoalkyl naphthols; Multicomponent reactions; Solventfree conditions;
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