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http://dx.doi.org/10.5012/bkcs.2011.32.2.609

Simple Synthetic Manipulation Allowing for Morphological Diversity of Porphyrin-Based Microcrystals  

Lee, Jun-Ho (Department of Chemistry, Korea University)
Ryu, Eui-Hyun (Department of Chemistry, Korea University)
Kim, Sung-Tae (Department of Chemistry, Korea University)
Lee, Suk-Joong (Department of Chemistry, Korea University)
Publication Information
Bulletin of the Korean Chemical Society / v.32, no.2, 2011 , pp. 609-612 More about this Journal
Abstract
Amphiphilic (porphyrin)Sn$(OH)_2$ molecular building block can directly translate into well-defined solid-state microcrystalline structures. The crystalline diamond plates are obtained from ethanol and crystalline square plates are grown from methanol solution. With a simple synthetic manipulation during the microcrystal growth, the morphologies can be controlled by adopting different molecular packing. Consequently, morphologies of microcrystals have been diversified. Furthermore, the macroscopic crystals were obtained in the presence of cetyltrimethylammonium bromide (CTAB).
Keywords
Amphiphilic; Porphyrin; Building block; Nanocrystalline; CTAB;
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