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http://dx.doi.org/10.5012/bkcs.2011.32.2.472

The Use of Sodium Chlorate/Hydrochloric Acid Mixtures as a Novel and Selective Chlorination Agent  

Moon, Byung-Seok (Department of Chemistry, Inha University)
Choi, Han-Young (Department of Chemistry, Inha University)
Koh, Hun-Yeong (Department of Chemistry, Inha University)
Chi, Dae-Yoon (Department of Chemistry, Sogang University)
Publication Information
Bulletin of the Korean Chemical Society / v.32, no.2, 2011 , pp. 472-476 More about this Journal
Abstract
Sodium chlorate/hydrochloric acid mixtures were used to chlorinate activated arenes and the $\alpha$-position of ketones. This chlorination method was used to produce selectively mono-, di-, and trichlorinated compounds by controlling the molarity of sodium chlorate. This reagent proved to be much more efficient and easier to handle than chlorine gas.
Keywords
Sodium chlorate; Chlorination agent; Sodium chlorate/HCl; Chlorination of aromatics; Chlorination of ketones;
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