Browse > Article
http://dx.doi.org/10.5012/bkcs.2011.32.11.3904

Synthesis, Structure, and Peroxidase Activity of an Octahedral Ru(III) Complex with a Tripodal Tetraamine Ligand  

Cho, Jang-Hoon (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University)
Kim, Kwan-Mook (Department of Chemistry and Nano Sciences, Ewha Womans University)
Noh, Dong-Youn (Department of Chemistry, Seoul Women's University)
Lee, Hong-In (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University)
Publication Information
Bulletin of the Korean Chemical Society / v.32, no.11, 2011 , pp. 3904-3908 More about this Journal
Abstract
A new octahedral Ru(III) complex with a tripodal tetraamine ligand, tpea = tris[2-(1-pyrazoyl)ethyl]amine, has been prepared and characterized. The single crystal X-ray crystallographic study of the complex revealed that the complex has a near octahedral geometry with the tetradentate ligand and two chloride ions. Peroxidase activity was examined by observing the oxidation of 2,2'-azinobis(3-ethylbenzothiazoline)-6-sulfonic acid (ABTS) with hydrogen peroxide in the presence of the complex. Amount of $ABTS^{+{\bullet}}$ generated during the reaction was monitored by UV/VIS and EPR spectroscopies. After the initiation of the peroxidase reaction, $ABTS^{+{\bullet}}$ concentration increases and then decreases after certain time, indicating that both ABTS and $ABTS^{+{\bullet}}$ are the substrates of the peroxidase activity of the Ru(III) complex.
Keywords
Ruthenium(III) complex; Antioxidant; Tetradentate ligand; Crystal structure;
Citations & Related Records

Times Cited By Web Of Science : 1  (Related Records In Web of Science)
Times Cited By SCOPUS : 1
연도 인용수 순위
  • Reference
1 Lentz, F.; Drescher, A.; Lindauer, A.; Henke, M.; Hilger, R. A.; Hartinger, C. G.; Scheulen, M. E.; Dittrich, C.; Keppler, B. K.; Jaehde, U. Anti-Cancer Drugs. 2009, 20, 97-103.   DOI   ScienceOn
2 Bratsos, L.; Jedner, S.; Gianferrara, T.; Alessio, E. Chim. Intern. J. Chem. 2007, 61, 692-697.   DOI
3 Alessio, E.; Mestroni, G.; Bergamo, A.; Sava, G. Curr. Topics in Med. Chem. 2004, 4, 1525-1535.   DOI   ScienceOn
4 Blackman, A. G. Polyhedron. 2005, 24, 1-39.   DOI   ScienceOn
5 Sorrell, T. N.; Jameson, D. L. Inorg. Chem. 1982, 21, 1014-1019.   DOI
6 Sheldrick, G. M. SHELXTL-PLUS; Crystal Structure Analysis Package, Bruker Analytical X-Ray, Madison, WI, USA, 1997.
7 Maneiro, M.; Bermejo, M. R.; Sousa, A.; Fondo, M.; Gonzalez, A. M.; Sousa-Pedrares, A.; McAuliffe, C. A. Polyhedron 2000, 19, 47-54.   DOI   ScienceOn
8 Zipplies, M. F.; Lee, W. A.; Bruice, T. C. J. Am. Chem. Soc. 1986, 108, 4433-4445.   DOI
9 Scarpellini, M.; Toledo, C. T., Jr.; Neves, A.; Ellena, J.; Castellano, E. E.; Franco, D. W. Inorg. Chim. Acta 2004, 357, 707-715.   DOI   ScienceOn
10 Murali, M.; Mayilmurugan, R.; Palaniandavar, M. Eur. J. Inorg. Chem. 2009, 3238-3249.
11 Che, C.-M.; Yam, V. W.-W.; Mak, T. C. W. J. Am. Chem. Soc. 1990, 112, 2284-2291.   DOI
12 Kojima, T.; Amano, T.; Ishii, Y.; Ohba, M.; Okaue, Y.; Matsuda, Y. Inorg. Chem. 1998, 37, 4076-4085.   DOI   ScienceOn
13 Sugimoto, H.; Matsunami, C.; Koshi, C.; Yamasaki, M.; Umakoshi, K.; Sasaki, Y. Bull. Chem. Soc. Japan 2001, 74, 2091-2099.   DOI   ScienceOn
14 Hartshorn, R. M.; House, D. A. J. Chem. Soc., Dalton Trans. 1998, 2577-2588.
15 Corey, E. J.; Bailar, J. C., Jr., J. Am. Chem. Soc. 1959, 81, 2620- 2629.   DOI
16 Ward, M. D. Coord. Chem. Rev. 2006, 250, 3128-3141.   DOI   ScienceOn
17 Clarke, M. J. Coord. Chem. Rev. 2003, 236, 209-233.   DOI   ScienceOn
18 Sakai, K.; Yamada, Y.; Tsubomura, T. Inorg. Chem. 1996, 35, 3163-3172.   DOI   ScienceOn
19 Chatterjee, D. Coord. Chem. Rev. 2008, 252, 176-198.   DOI   ScienceOn
20 Concepcion, J. J.; Jurss, J. W.; Templeton, J. L.; Meyer, T. J. J. Am. Chem. Soc. 2008, 130, 16462-16463.   DOI   ScienceOn
21 Dyson, P. J.; Sava, G. J. Chem. Soc., Dalton Trans. 2006, 1929- 1933.
22 Hartinger, C. G.; Zorbas-Seifried, S.; Jakupec, M. A.; Kynast, B.; Zorbas, H.; Keppler, B. K. J. Inorg. Biochem. 2006, 100, 891-904.   DOI   ScienceOn
23 Solis-Oba, M.; Ugalde-Saldivar, V. M.; Gonzalez, I.; Viniegra- Gonzalez, G. J. Electroanal. Chem. 2005, 579, 59-66.   DOI   ScienceOn
24 Bermejo, M. R.; Fernandez, M. I.; Gonzalez-Noya, A. M.; Maneiro, M.; Pedrido, R.; Rodriguez, A. J.; Garcia-Monteagudo, J. C.; Donnadieu, B. J. Inorg. Biochem. 2006, 100, 1470-1478.   DOI   ScienceOn
25 Maneiro, M.; Bermejo, M. R.; Fernandez, M. I.; Gomez-Forneas, E.; Gonzalez-Noya, A. M.; Tyryshkin, A. M. New J. Chem. 2003, 27, 727-733.   DOI   ScienceOn
26 Bermejo, M. R.; Fernandez, M. I.; Gomez-Forneas, E.; Gonzalez- Noya, A.; Maneiro, M.; Rosa, P.; Rodriguez, M. J. Eur. J. Inorg. Chem. 2007, 3789-3797.
27 McGarvey, B. R. Coord. Chem. Rev. 1998, 170, 75-92.   DOI   ScienceOn
28 Chatterjee, D.; Nayak, K. A.; Ember. E.; van Eldik, R. J. Chem. Soc., Dalton Trans. 2010, 39, 1695-1698.   DOI   ScienceOn