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http://dx.doi.org/10.5012/bkcs.2011.32.10.3575

Controlled Assembly of Gold Nanoprism and Hexagonal Nanoplate Films for Surface Enhanced Raman Scattering  

Lee, Doo-Ri (Department of Chemistry, Sungkyunkwan University)
Hong, Soon-Chang (Department of Chemistry, Sungkyunkwan University)
Park, Sung-Ho (Department of Chemistry, Sungkyunkwan University)
Publication Information
Bulletin of the Korean Chemical Society / v.32, no.10, 2011 , pp. 3575-3580 More about this Journal
Abstract
This paper reports a methodology for preparing close-packed two dimensional gold nanoprism films and hexagonal nanoplate films at a hexane/water interface. By controlling the concentration of linker molecules in the hexane layer and the temperature of the colloid solution, highly ordered close-packed nanoplate arrays can be fabricated. These films were investigated to compare their corresponding surface enhanced Raman scattering (SERS) efficiencies. It was demonstrated that the Au nanoprism films resulted in a stronger SERS enhancement than the Au hexagonal nanoplate films. The difference in the SERS enhancement is attributed to the film array difference, demonstrating that Au nanoprism films have a higher line contact density than their Au hexagonal analogues.
Keywords
Gold nanoprism; Gold hexagonal nanoplate; Gold film; Surface enhanced Raman scattering;
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