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http://dx.doi.org/10.5012/bkcs.2010.31.9.2644

A Green Protocol for Catalytic Conversion of Epoxides to 1,2-Diacetoxy Esters with Phosphomolybdic Acid Alone or Its Supported on Silica Gel  

Zeynizadeh, Behzad (Department of Chemistry, Faculty of Science, Urmia University)
Sadighnia, Leila (Department of Chemistry, Faculty of Science, Urmia University)
Publication Information
Bulletin of the Korean Chemical Society / v.31, no.9, 2010 , pp. 2644-2648 More about this Journal
Abstract
Catalytic conversion of structurally different epoxides to the corresponding 1,2-diacetoxy esters was carried out readily with phosphomolybdic acid alone or its supported on $SiO_2$. The reactions were carried out under solvolytic or solvent free conditions within 5-15 min at room temperature. The product 1,2-diacetates were obtained in high to excellent yields. Supporting of phosphomolybdic acid on $SiO_2$ showed the better catalytic activity than $Al_2O_3$. Conversion of optically pure R-(+)-styrene oxide to S-(+)-1,2-diacetoxy-1-phenylethane was carried with phosphomolybdic acid in high yield and stereospecificity.
Keywords
Epoxide; 1,2-Diacetoxy esters; Phosphomolybdic acid; $SiO_2$; $Al_2O_3$;
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