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http://dx.doi.org/10.5012/bkcs.2010.31.8.2158

Delicate Difference in Coordinating Nature between Copper(II) and Nickel(II) Ions. Structural Properties of Copper(II) and Nickel(II) Nitrate Containing 1,2-Bis(dimethyl-3-pyridylsilyl)ethane  

Kim, Shin-A (Department of Chemistry, Pusan National University)
Kim, Chi-Won (Department of Chemistry, Pusan National University)
Noh, Tae-Hwan (Department of Chemistry, Pusan National University)
Lee, Young-A (Department of Chemistry, Chonbuk National University)
Jung, Ok-Sang (Department of Chemistry, Pusan National University)
Publication Information
Bulletin of the Korean Chemical Society / v.31, no.8, 2010 , pp. 2158-2162 More about this Journal
Abstract
Studies on the molecular construction and structures of $M(NO_3)_2$ (M = Cu(II), Ni(II)) complexes with 1,2-bis(dimethyl-3-pyridylsilyl)ethane (L) have been carried out. Formation of each molecular skeleton appears to be primarily associated with a suitable combination of bidentate N-donors of L and coordinating nature of octahedral metal(II) ions: [$Cu(NO_3)_2(L)_2$] yields a 2-dimensional sheet structure consisting of 44-membered $Cu_4L_4$ skeleton whereas $[Ni(L)_2(H_2O)_2](NO_3)_2$ produces an interpenetrated 3-dimensional structure consisting of 66-membered cyclohexanoid ($M_6L_6$) skeleton. The Cu(II) ion prefers nitrate whereas the Ni(II) ion prefers water molecules as the fifth and the sixth ligands.
Keywords
1,2-Bis(dimethyl-3-pyridylsilyl)ethane; Coordinating nature; Copper(II); Interpenetration; Nickel(II);
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