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http://dx.doi.org/10.5012/bkcs.2010.31.7.1968

Amperometric Morphine Detection Using Pt-Co Alloy Nanowire Array-modified Electrode  

Tao, Manlan (College of Chemistry and Chemical Engineering, Yunnan Normal Universityiversity)
Xu, Feng (College of Chemistry and Chemical Engineering, Yunnan Normal University)
Li, Yueting (College of Chemistry and Chemical Engineering, Yunnan Normal University)
Xu, Quanqing (College of Chemistry and Chemical Engineering, Yunnan Normal University)
Chang, Yanbing (College of Chemistry and Chemical Engineering, Yunnan Normal University)
Wu, Zaisheng (State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University)
Yang, Yun-Hui (College of Chemistry and Chemical Engineering, Yunnan Normal University)
Publication Information
Abstract
Pt-Co alloy nanowire array was directly synthesized by electrochemical deposition with polycarbonate template at -1.0V and subsequent chemical etching of the template. The use of Pt-Co alloy nanowire array-modified electrode (Pt-Co NAE) for the determination of morphine (MO) is described. The morphology of the Pt-Co alloy nanowire array has been investigated by scanning electron microscopy (SEM) and energy disperse X-ray spectroscopy (EDS) analysis), respectively. The resulting Pt-Co NAE offered a linear amperometric response for morphine ranging from $2.35\times10^{-5}$ to $2.39\times10^{-3}$ M with a detection limit of $7.83\times10^{-6}$ M at optimum conditions. This sensor displayed high sensitivity and long-term stability.
Keywords
Morphine; Pt-Co alloy; Nanowire array; Amperometric; Electrode;
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