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http://dx.doi.org/10.5012/bkcs.2010.31.5.1326

Studies of Inter/intramolecular Weak Interactions with CH… S; and S…arene Interaction in Symmetrical and Dissymmetrical Models  

Dubey, Rashmi (Department of Chemistry, Faculty of Science, Banaras Hindu University)
Tewari, Ashish K. (Department of Chemistry, Faculty of Science, Banaras Hindu University)
Ravikumar, K. (Laboratory of X-ray Crystallography, Indian Institute of Chemical Technology)
Sridhar, B. (Laboratory of X-ray Crystallography, Indian Institute of Chemical Technology)
Publication Information
Abstract
Evidences have proved the versatile role of sulfur atom in supramolecular chemistry. $^1$Presence of S atom in the molecule usually results in the specific structural properties of molecules. In the present study, $S{\cdots}arene$, $N{\cdots}arene$, $CH{\cdots}{\pi}$, $CH{\cdots}S$ and $CH{\cdots}N$ type of weak interactions stabilize the conformation and self assembly of symmetrical as well as dissymmetrical molecules.
Keywords
Intermolecular interaction; Intramolecular interaction; Weak interactions; Self assembly; Substituent effect;
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