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http://dx.doi.org/10.5012/bkcs.2010.31.5.1280

Asymmetric Michael Addition of Ketones to Nitroolefins Catalyzed by a New Chiral Catalyst  

Wang, Lian-Jun (College of Chemistry and Chemical Engineering, Hunan Institute of Engineering)
Hu, Feng-Feng (College of Chemistry and Chemical Engineering, Hunan Institute of Engineering)
Publication Information
Bulletin of the Korean Chemical Society / v.31, no.5, 2010 , pp. 1280-1282 More about this Journal
Abstract
A new chiral catalyst was synthesized and found that it could catalyzed the asymmetric Michael reaction of ketones with nitroolefins smoothly at room temperature, giving the desired adducts in 71 - 92% yields with excellent diastereoselectivities and high enantioselectivities (up to 95% ee).
Keywords
Chiral catalyst; Michael reaction; Nitroolefin; Ketone; Enantioselectivity;
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