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http://dx.doi.org/10.5012/bkcs.2010.31.03.653

Enantioselective Total Synthesis of (-)-Clavosolide A and B  

Son, Jung-Beom (Department of Chemistry, Sogang University)
Kim, Si-Nae (Department of Chemistry, Sogang University)
Kim, Na-Yeong (Department of Chemistry, Sogang University)
Hwang, Min-Ho (Department of Chemistry, Sogang University)
Lee, Won-Sun (Department of Chemistry, Sogang University)
Lee, Duck-Hyung (Department of Chemistry, Sogang University)
Publication Information
Bulletin of the Korean Chemical Society / v.31, no.3, 2010 , pp. 653-663 More about this Journal
Abstract
Enantioselective total synthesis of (-)-clavosolide A and B was reported in full including the synthesis of proposed structure of (-)-clavosoldie A (1), revised structure of (-)-clavosoldie A (5), and revised structure of (-)-clavosoldie B (6). The relative and absolute stereochemistries of the natural products were confirmed unambiguously by comparing the optical rotation values and $^1H$ and $^{13}C$ NMR spectra of them.
Keywords
Enantioselective total synthesis; Clavosolide A; Clavosolide B;
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