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http://dx.doi.org/10.5012/bkcs.2010.31.01.140

Simultaneous Detection of Cd (II), Pb (II), Cu (II), and Hg (II) Ions in Dye Waste Water Using a Boron Doped Diamond Electrode with DPASV  

Yoon, Jang-Hee (Busan Center, Korea Basic Science Institute)
Yang, Jee-Eun (Department of Chemistry, Pusan National University)
Kim, Jong-Phil (Busan Center, Korea Basic Science Institute)
Bae, Jong-Seong (Busan Center, Korea Basic Science Institute)
Shim, Yoon-Bo (Department of Chemistry, Pusan National University)
Won, Mi-Sook (Busan Center, Korea Basic Science Institute)
Publication Information
Abstract
The simultaneous detection of Cd (II), Pb (II), Cu (II), and Hg (II) ions in aqueous medium using a BDD electrode with DPASV is described. XPS was used to characterize the chemical states of trace metal ions deposited on the BDD electrode surface. Experimental parameters that affect response, such as pH, deposition time, deposition potential, and pulse amplitude were carefully optimized. The detection limits for Cd (II), Pb (II), Cu (II), and Hg (II) ions were 3.5 ppb, 2.0 ppb, 0.1 ppb and 0.7 ppb, respectively. The application of the BDD electrode on the electrochemical pretreatment for the simultaneous metal detection in the dye waste water was also investigated.
Keywords
Boron doped diamond (BDD) electrode; Differential pulse anodic stripping voltammetry (DPASV); Trace metal ions; Waste water;
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