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http://dx.doi.org/10.5012/bkcs.2010.31.12.3765

Selective Oxidation of Olefins Catalyzed by Polymer-anchored Nickel(II) Complex in Water Medium  

Islam, Manirul (Department of Chemistry, University of Kalyani)
Hossain, Dildar (Department of Chemistry, University of Kalyani)
Mondal, Paramita (Department of Chemistry, University of Kalyani)
Roy, Anupam Singha (Department of Chemistry, University of Kalyani)
Mondal, Sanchita (Department of Chemistry, University of Kalyani)
Mobarak, Manir (Department of Chemistry, University of Kalyani)
Publication Information
Bulletin of the Korean Chemical Society / v.31, no.12, 2010 , pp. 3765-3770 More about this Journal
Abstract
Selective oxidation of olefins has been carried out in water medium with tert-butylhydroperoxide (TBHP, 70% aqueous) as an oxidant using polymer-anchored Ni(II) complex as a catalyst. Several parameters were varied to optimize the reaction conditions. Under the optimized reaction conditions olefins gave selectively allylic oxidation products. The present polymer anchored Ni(II) complex can be recycled five times without any appreciable loss in catalytic activity.
Keywords
Chloromethylated polystyrene; Nickel (II) complex; Olefin oxidation; Water; TBHP;
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