Browse > Article
http://dx.doi.org/10.5012/bkcs.2010.31.12.3765

Selective Oxidation of Olefins Catalyzed by Polymer-anchored Nickel(II) Complex in Water Medium  

Islam, Manirul (Department of Chemistry, University of Kalyani)
Hossain, Dildar (Department of Chemistry, University of Kalyani)
Mondal, Paramita (Department of Chemistry, University of Kalyani)
Roy, Anupam Singha (Department of Chemistry, University of Kalyani)
Mondal, Sanchita (Department of Chemistry, University of Kalyani)
Mobarak, Manir (Department of Chemistry, University of Kalyani)
Publication Information
Abstract
Selective oxidation of olefins has been carried out in water medium with tert-butylhydroperoxide (TBHP, 70% aqueous) as an oxidant using polymer-anchored Ni(II) complex as a catalyst. Several parameters were varied to optimize the reaction conditions. Under the optimized reaction conditions olefins gave selectively allylic oxidation products. The present polymer anchored Ni(II) complex can be recycled five times without any appreciable loss in catalytic activity.
Keywords
Chloromethylated polystyrene; Nickel (II) complex; Olefin oxidation; Water; TBHP;
Citations & Related Records

Times Cited By Web Of Science : 1  (Related Records In Web of Science)
Times Cited By SCOPUS : 1
연도 인용수 순위
1 Antony, R.; Tembe, G. L.; Ravindranathana, M.; Ram, R. N. Eur.Polym. J. 2000, 36, 1579.   DOI   ScienceOn
2 Bellamy, L. J., Ed.; Infra-red Spectra of Complex Molecules; Chapman and Hall: London, 1975.
3 Gauli, K.; Ram, R. N.; Soni, H. P. J. Mol. Catal. A: Chem. 2005, 242, 161.   DOI   ScienceOn
4 Colchoubian, H.; Waltz, W. L.; Quail, J. W. Can. J. Chem. 1999, 77, 37.
5 Sacconi, L. Trans. Met. Chem. 1968, 61, 943.
6 Sen, R.; Bhunia, S.; Mal, D.; Koner, S.; Miyashita, Y.; Okamoto, K. Langmuir 2009, 25, 13667.   DOI   ScienceOn
7 Sherrington, D. C. Pure Appl. Chem. 1988, 60, 401.   DOI   ScienceOn
8 Annis, D. A.; Jacobson, E. N. J. Am. Chem. Soc. 1999, 121, 4147.   DOI   ScienceOn
9 Canali, L.; Sherrington, D. C. Chem. Soc. Rev. 1999, 28, 85.   DOI   ScienceOn
10 Sherrington, D. C. Catal. Today 2000, 57, 87   DOI   ScienceOn
11 Islam, M.; Mondal, P.; Mondal, S.; Mukherjee, S.; Roy, A. S.; Mobarak, M.; Paul, M. J. Inorg. Organomet. Polym. 2010, 20, 87.   DOI
12 Valodkar, V. B.; Tembe, G. L.; Ravindranathan, M.; Ram, R. N.;Rama, H. S. J. Mol. Catal A: Chem. 2004, 208, 21.   DOI   ScienceOn
13 Mukherjee, S.; Samanta, S.; Bhaumik, A.; Roy, B. C. Appl. Catal. B Environ. 2006, 68, 12.   DOI   ScienceOn
14 Mukherjee, S.; Samanta, S.; Roy, B. C.; Bhaumik, A. Appl. Catal.A Gen. 2006, 301, 79.   DOI   ScienceOn
15 Sohrabi, H.; Esmaeeli, M.; Farzaneh, F.; Ghandi, M. J. Inclusion Phenomena and Macrocyclic Chem. 2006, 54, 23.   DOI
16 Sheldon, R. A.; Kochi, J. K. Metal Complex Catalyzed Oxidation of Organic Compounds; Academic Press: New York, 1981.
17 Cainelli, G.; Cardillo, G. Chromium Oxidation in Organic Chemistry; Springer-Verlag: New York, 1984.
18 Kroschwitz, J. I.; Othmer, K. Encyclopedia of Chemical Technology; Wiley-Interscience: New York, 1992.
19 Ullmann, F. Ullmanns Encyclopedia of Industrial Chemistry;Wiley-VCH: Verlag, Weinheim, Germany, 2003.
20 Gokak, D. T.; Kamath, B. V.; Ram, R. N. J. Appl. Polym. Sci. 1988,35, 1523.   DOI   ScienceOn
21 Angelino, M. D.; Laibinis, P. E. Macromolecules 1998, 31, 7581.   DOI   ScienceOn
22 Clark, J. H.; Tavener, S. J. Org. Process Res. Dev. 2007, 11, 149.   DOI   ScienceOn
23 Li, C. J. Green Chem. 2008, 10, 151.   DOI   ScienceOn
24 Azizi, N.; Aryanasab, F.; Torkiyan, L.; Ziyaei, A.; Saidi, M. R. J.Org. Chem. 2006, 71, 3634.   DOI   ScienceOn
25 Horvath, I. T. Green Chem. 2008, 10, 1024.   DOI   ScienceOn
26 Pirrung, M. C. Chem. Eur. J. 2006, 12, 1312.   DOI   ScienceOn
27 Shapiro, N.; Vigalok, A. Angew. Chem., Int. Ed. 2008, 47, 2849.   DOI   ScienceOn
28 Starks, C. M. J. Am. Chem. Soc.1971, 93,195.   DOI
29 Regen, S. L. J. Am. Chem. Soc. 1976, 98, 6270   DOI
30 Meunier, M. Chem. Rev. 1992, 92, 1411.   DOI
31 Sherrington, D. C., Hodnett, B. K., Keybett, A. P., Clark, J. H., Smith, K., Eds.; Supported Reagents and Catalyst in Chemistry; Royal Society of Chemistry: Cambridge, 1998; p 220.
32 Islam, M.; Mondal, P.; Mukherjee, S.; Mobarak, M.; Roy, A. S.; Mondal, S.; Sarkar, S. J. Chem. Technol. Biotechnol. 2010, 85, 460.