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http://dx.doi.org/10.5012/bkcs.2010.31.12.3611

New 7-Hydroxycoumarin-Based Fluorescent Chemosensors for Zn(II) and Cd(II)  

Swamy, K.M.K. (Department of Chemistry and Nano Science (BK21) and Department of Bioinspired Science (WCU), Ewha Womans University)
Kim, Min-Jung (Department of Chemistry and Nano Science (BK21) and Department of Bioinspired Science (WCU), Ewha Womans University)
Jeon, Hye-Ryeong (Department of Chemistry and Nano Science (BK21) and Department of Bioinspired Science (WCU), Ewha Womans University)
Jung, Ji-Young (Department of Chemistry and Nano Science (BK21) and Department of Bioinspired Science (WCU), Ewha Womans University)
Yoon, Ju-Young (Department of Chemistry and Nano Science (BK21) and Department of Bioinspired Science (WCU), Ewha Womans University)
Publication Information
Bulletin of the Korean Chemical Society / v.31, no.12, 2010 , pp. 3611-3616 More about this Journal
Abstract
Five new 4- or 8-substituted-7-hydroxycoumarin derivatives (1-5) were synthesized as fluorescent sensors for metal ions. Fluorescent changes and selectivity for metal ions were compared based on the introduction of different ligands and/or testing with different substitution positions of 7-hydroxycoumarin in aqueous solution. Especially, probes 2, 3 and 5 displayed large fluorescence enhancements with $Zn^{2+}$ and $Cd^{2+}$. Probes 2 and 3 showed moderate selectivity for $Zn^{2+}$ over $Cd^{2+}$. On the other hand, probe 4 showed large fluorescence quenching effects upon the addition of $Ag^+$ and $Hg^{2+}$.
Keywords
Fluorescent chemosensors; Coumarin; $Zn^{2+}$ sensor; $Cd^{2+}$ sensor; Fluorescence;
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