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http://dx.doi.org/10.5012/bkcs.2009.30.8.1832

The Rapid and Efficient Synthesis of Bromohydrins from Olefins under HBr/H2O2 System by Visible Light Induced  

Tang, Rui-Ren (School of Chemistry and Chemical Engineering, Central South University)
Gong, Nian-Hua (School of Chemistry and Chemical Engineering, Central South University)
Publication Information
Bulletin of the Korean Chemical Society / v.30, no.8, 2009 , pp. 1832-1834 More about this Journal
Abstract
A simple and safe method has been presented for conversion of olefins into bromohydrins using hydrogen bromide and hydrogen peroxide as bromide source by visible light induced within a very short time to get high yield bromohydrins along with a little mount dibromo-product. In this paper, cyclohexene is firstly carried out as the model substrate and investigated the bromination under HBr/$H_2O_2$ system using 150 W incandescent light irradiated in C$Cl_4$ within short time to get good yield of 2-bromocyclohexanol along with a little mount of 1,2-dibromocyclohexane; then, a series of alkenes are brominated to corresponding bromohydrins using the same protocol.
Keywords
Alkenes; Bromohydrin; Dibromination; Hydrogen bromide; Hydrogen peroxide;
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