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http://dx.doi.org/10.5012/bkcs.2009.30.7.1583

Efficient Biomimetic Oxidative Decarboxylation of Some Carboxylic Acids Catalyzed by a Manganese (III) Schiff Base Complex  

Nasr-Esfahani, Masoud (Department of Chemistry, Yasouj University)
Montazerozohori, Morteza (Department of Chemistry, Yasouj University)
Akhlaghi, Parisa (Department of Chemistry, Yasouj University)
Publication Information
Bulletin of the Korean Chemical Society / v.30, no.7, 2009 , pp. 1583-1587 More about this Journal
Abstract
The four dentate $N_2O_2$ Schiff base ligand of bis(2-hydroxyacetophenone)-1,2-propanediimine (BHAPN) and its manganese (III) complex were synthesized and identified by microanalysis, spectral data ($^1H$ NMR, MS, FT-IR and UV-Visible) and molar conductivity measurement. The mild and efficient homogeneous oxidative decarboxylation of some carboxylic acids by catalytic amount of this manganese (III) complex, using tetrabutylamonium periodate as a mild oxidant in chloroform at room temperature is reported. The catalyst used in this study showed good activity for the decarboxylation of the titled compounds.
Keywords
Schiff base; Complex; Catalytic; Decarboxylation; Manganese(III);
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