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http://dx.doi.org/10.5012/bkcs.2009.30.6.1317

Highly Enantioselective Rh-catalyzed Transfer Hydrogenation of α-Functionalized Arylketones  

Lee, Do-Min (Bio-Organic Science Division, Korea Research Institute of Chemical Technology)
Kwak, Se-Hun (Bio-Organic Science Division, Korea Research Institute of Chemical Technology)
Lee, Kee-In (Bio-Organic Science Division, Korea Research Institute of Chemical Technology)
Publication Information
Bulletin of the Korean Chemical Society / v.30, no.6, 2009 , pp. 1317-1324 More about this Journal
Abstract
Asymmetric transfer hydrogenation of α-functionalized arylketones has been studied. The chiral Rh-catalyst effectively performed in transfer hydrogenation of $\alpha$-mesyloxyketones with an azeotropic mixture of formic acid/triethylamine to produce optically active 1-arylethandiols with excellent enantioselectivity.
Keywords
Asymmetric transfer hydrogenation; $\alpha$-Mesyloxy arylketone; Arylethandiol;
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Times Cited By Web Of Science : 6  (Related Records In Web of Science)
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