Browse > Article
http://dx.doi.org/10.5012/bkcs.2009.30.5.1157

Crystal Structures and Luminescence Properties of Pd(II) and Pt(II) Complexes with 2,5-Bis(thiophene)-1-nonyl-3,4-bis(methylthio)pyrrole  

Kang, Jun-Gill (Department of Chemistry, Chungnam National University)
Oh, Sung-Il (Department of Chemistry, Chungnam National University)
Cho, Dong-Hee (Department of Chemistry, Chungnam National University)
Nah, Min-Kook (Department of Chemistry, Chungnam National University)
Park, Chang-Moon (Department of Chemistry, Chungnam National University)
Bae, Young-Ju (Department of Chemistry, Kwangwoon University)
Woo, Tack-Han (Department of Chemistry, Kwangwoon University)
Park, Young-Jin (Department of Chemistry, Kwangwoon University)
Lee, Sang-Woo (Department of Chemistry, Kwangwoon University)
Kim, In-Tae (Department of Chemistry, Kwangwoon University)
Publication Information
Bulletin of the Korean Chemical Society / v.30, no.5, 2009 , pp. 1157-1163 More about this Journal
Abstract
Complexes of Pd(btnbmtp)$Cl_2$ and Pt(btnbmptp)$Cl_2$ (btnbmtp = 2,5-bis(thiophen)-1-nonyl-3,4-bis(methylthio)- pyrrole) were prepared and their crystal structures were determined at room temperature. In the structures, the two thiophene moieties lie in cis form with an average dihedral angle of $55.26^{\circ}$ to the pyrrole frame. The luminescence properties of the free ligand and the complexes were investigated in solution and solid states. The luminescence of the compounds were not favored by substituting thiophene moieties to the pyrrole frame, compared to the unsubstituted nbmptp (nbmptp = 1-nonyl-3,4-bis(methylthio)pyrrole). In particular, thiophene substitution quenched the emission from the complexes dissolved in ,$CH_2Cl_2$ and reduced the charge transfer transitions from S atoms of the thio moieties to Pt in crystalline state, which was very characteristic of Pt(nbmptp)$Cl_2$.
Keywords
2,5-Bis(thiophen)-1-nonyl-3,4-bis(methylthio)pyrrole; Pt(II); Pd(II); X-ray structure; Luminescence;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
Times Cited By Web Of Science : 1  (Related Records In Web of Science)
Times Cited By SCOPUS : 2
연도 인용수 순위
1 Cheylan, S.; Bolink, H. J.; Fraleoni-Morgera, A.; Puigdollers, J.; Voz, C.; Mencarelli, I.; Setti, L.; Alcubilla, R.; Badenes, G. Org. Electronics 2007, 8, 641   DOI   ScienceOn
2 Qi, Z.-J.; Feng, W.-D.; Sun, Y.-M.; Yan, D.-Z.; He, Y.-F.; Yu, J. J. Mater. Sci.: Mater. Electronics 2007, 18, 869   DOI   ScienceOn
3 Matsushima, T.; Adachi, C. Chem. Mater. 2008, 20, 2881   DOI   ScienceOn
4 Zhou, Q.; Li, C. M.; Li, J.; Cui, X.; Gervasio, D. J. Phys. Chem. C 2007, 111, 11216   DOI   ScienceOn
5 Henderson, J. C.; Kiya, Y.; Hutchison, G. R.; Abruna, H. D. J. Phys. Chem. C 2008, 112, 3989   DOI   ScienceOn
6 Li, H.; Lambert, C.; Stahl, R. Macromol. 2006, 39, 2049   DOI   ScienceOn
7 Goldoni, F.; Antolini, L.; Pourtois, G.; Schenning, A. P. H. J.; Janssen, R. A. J.; Lazzaroni, R.: Brédas, J.-L.; Meijer, E. W. Eur. J. Inorg. Chem. 2001, 821
8 Matthews, J. R.; Goldoni, F.; Kooijman, H.; Spek, A. L.; Schenning, A. P. H. J.; Meijer, E. W. Macromol. Rapid Comm. 2007, 28, 1809   DOI   ScienceOn
9 Kang, J.-G.; Cho, D.-H.; Park, C.; Kang, S. K.; Kim, I. T.; Lee, S. W.; Lee, H. H.; Lee, Y. N.; Lim, D. W.; Lee, S. J.; Kim, S. H.; Bae, Y. J. Bull. Korean Chem. Soc. 2008, 29, 599   DOI   ScienceOn
10 Kang, J.-G.; Cho, H.-K.; Park, C.; Kang, S. K.; Kim, I. T.; Lee, S. W.; Lee, H. H.; Lee, Y. N.; Cho, S. H.; Lee, J. H.; Lee, S. H. Bull. Korean Chem. Soc. 2008, 29, 679   DOI   ScienceOn
11 Richards, J. J.; Melander, C. J. Org. Chem. 2008, 73, 5191   DOI   ScienceOn
12 Sheldrick, G. M. Program SADABS; Area-detector absorption correction University of Gottingen: Gottingen, Germany, 1996
13 SHELXTL, 5.030 ed.; Brucker Analytical X-ray Instruments, Inc.: Madison, WI, 1998
14 Sheldrick, G. M. SHELXS-97, SHELXL-97, Programs for Crystal Structure Analysis; University of Gottingen: Gottingen, Germany, 1997
15 Brabec, C. J.; Winder, C.; Sariciftci, N. S.; Hummelen, J. C.; Dhanabalan, A.; Van Hal, P. A.; Janssen, R. A. J. Adv. Funct. Mater. 2002, 12, 709   DOI   ScienceOn
16 Hissler, M.; Lescop, C.; Reau, R. Pure Appl. Chem. 2005, 77, 2099   DOI   ScienceOn
17 Kang, J.-G.; Cho, H.-G.; Kang, S. K.; Park, C.; Lee, S. W.; Park, G. B.; Lee, J. S.; Kim, I. T. J. Photochem. Photobio. A : Chem. 2006, 183, 212   DOI   ScienceOn
18 Rudge, A.; Raistrick, I.; Gottesfeld, S.; Ferraris, J. P. Electrochim. Acta 1994, 39, 273   DOI   ScienceOn
19 Henderson, J. C.; Kiya, Y.; Hutchison, G. R.; Abruna, H. D. J. Phys. Chem. C 2008, 112, 3989   DOI   ScienceOn
20 Guernion, N. J. L.; Hayes, W. Curr. Org. Chem. 2004, 8, 637   DOI   ScienceOn
21 Sergawie, A.; Admassie, S.; Mammo, W.; Yohannes, T.; Solomon, T. Syn. Metals 2008, 158, 307   DOI   ScienceOn
22 Nielsen, C. B.; Angerhofer, A.; Abboud, K. A.; Reynolds, J. R. J. Am. Chem. Soc. 2008, 130, 9734   DOI   ScienceOn
23 Ma, C.; Taya, M.; Xu, C. Electrochim. Acta 2008, 54, 598   DOI   ScienceOn
24 Johansson, T.; Mammo, W.; Svensson, M.; Andersson, M. R.; Inganas, O. Chem. Mater. 1999, 11, 3133   DOI   ScienceOn
25 Egbe, D. A. M.; Nguyen, Le. H.; Muehlbacher, D.; Hoppe, H.; Schmidtke, K.; Sariciftci, N. S. Thin Solid Films 2006, 511, 486   DOI   ScienceOn
26 Zhou, E.; Tan, Z.; Huo, L.; He, Y.; Yang, C.; Li, Y. J. Phys. Chem. B 2006, 110, 26062   DOI   ScienceOn
27 Li, G.; Jiang, K.-J.; Li, Y.-F.; Li, S.-L.; Yang, L.-M. J. Phys. Chem. C 2008, 112, 11591   DOI   ScienceOn
28 Kuo, W.-J.; Chen, Y.-H.; Jeng, R.-J.; Chan, L.-H.; Lin, W.-P.; Yang, Z.-M. Tetrahedron 2007, 63, 7086   DOI   ScienceOn
29 Wu, S.-H.; Huang, H.-M.; Chen, K.-C.; Hu, C.-W.; Hsu, C.-C.; Tsiang, R. C.-C. Adv. Funct. Mater. 2006, 16, 1959   DOI   ScienceOn
30 Hobbs, M. G.; Baumgartner, T. Eur. J. Inorg. Chem. 2007, 3611
31 Kuila, B. K.; Garai, A.; Nandi, A. K. Chem. Mater. 2007, 19, 5443   DOI   ScienceOn