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http://dx.doi.org/10.5012/bkcs.2009.30.12.2969

Ammonium Metavanadate: A Mild and Efficient Catalyst for the Synthesis of Coumarins  

Mandhane, Priyanka G. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University)
Joshi, Ratnadeep S. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University)
Ghawalkar, Anant R. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University)
Jadhav, Ganesh R. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University)
Gill, Charansingh H. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University)
Publication Information
Bulletin of the Korean Chemical Society / v.30, no.12, 2009 , pp. 2969-2972 More about this Journal
Abstract
A mild and efficient method has been developed for condensation of substituted phenol with ${\beta}$-ketoester in the presence of catalytic amount of ammonium metavanadate (10 mol%) at ambient temperature to afford the corresponding substituted 4-methyl-2H-chromen-2-one in high yields under mild conditions. Utilization of commercially available inexpensive catalyst makes this manipulation very interesting from an economic perspective.
Keywords
Ammonium metavanadate; 4-Methyl-2H-chromen-2-one; ${\beta}$-Ketoester Pechmann condensation;
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