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http://dx.doi.org/10.5012/bkcs.2008.29.5.1033

Catalytic Oxidation of Cyclohexene with Hydrogen Peroxide over Cu(II)-Cyclam-SBA-16 Catalyst  

Prasetyanto, Eko Adi (Laboratory of Nano-Green Catalysis and Nano Center for Fine Chemicals Fusion Technology, Department of Chemistry, Inha University)
Park, Sang-Eon (Laboratory of Nano-Green Catalysis and Nano Center for Fine Chemicals Fusion Technology, Department of Chemistry, Inha University)
Publication Information
Bulletin of the Korean Chemical Society / v.29, no.5, 2008 , pp. 1033-1037 More about this Journal
Abstract
A copper cyclam-type complex was successfully immobilized onto mesoporous silica SBA-16. Characterization by NIR spectroscopy and TGA analysis confirmed that copper cyclam complex is immobilized onto mesoporous SBA-16. The Cu(II)-Cyclam-SBA-16 was proven to be a good catalyst for oxidation reaction of cyclohexene with conversion up to 77.8% after 13 h reaction and providing a high selectivity to cyclohexenol and 3-hydroperoxycyclohex-1-ene. The results suggest that the copper species play a major role as catalyst via reversible redox cycles as proven by cyclic voltammetry analysis.
Keywords
Oxidation; Copper; Cyclam; SBA-16
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Times Cited By KSCI : 2  (Citation Analysis)
Times Cited By Web Of Science : 4  (Related Records In Web of Science)
Times Cited By SCOPUS : 5
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