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http://dx.doi.org/10.5012/bkcs.2008.29.5.1018

Photoreactions of 2-(Pentamethyldisilanyloxy)phenylpentamethyldisilane  

Park, Seung-Ki (Department of Chemistry, College of Natural Sciences, The University of Suwon)
Publication Information
Bulletin of the Korean Chemical Society / v.29, no.5, 2008 , pp. 1018-1024 More about this Journal
Abstract
Photolysis of 2-(pentamethyldisilanyloxy)phenylpentamethyldisilane 1 in methanol provides five photoproducts 3, 4, 5, 6, and 7. Compounds 3 and 4 were probably formed from the methanol addition reactions of silene intermediate 2 and the formation of 5, 6, and 7 can best be explained by the nucleophilic attack of methanol to silicon atom in pentamethyldisilanyloxy or pentamethyldisilanyl group of the photoexcited state of 1. Irradiation of 1 in n-hexane gives a photoproduct 6 via silyl radical intermediate 8 and a novel intramolecular cyclization photoproduct 11 via silene 9 and silyl radical intermediate 10. Irradiation of 1 in deaerated methylene chloride in the presence of acetone affords a novel photoproduct 11 and phenol 7 but the expected photoproducts from the reaction of the silene intermediate with acetone were not obtained.
Keywords
2-(Pentamethyldisilanyloxy)phenylpentamethyldisilane; Silene
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
Times Cited By Web Of Science : 3  (Related Records In Web of Science)
Times Cited By SCOPUS : 0
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