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http://dx.doi.org/10.5012/bkcs.2008.29.1.094

Liquid-liquid Distribution of the Tetravalent Zirconium, Hafnium and Thorium with a New Tetradentate Naphthol-derivative Schiff Base  

Saberyan, Kamal (Chemistry Research Department, Nuclear Science Research School, Nuclear Science and Technology Research Institute)
Shamsipur, Mojtaba (Department of Chemistry, Razi University)
Zolfonoun, Ehsan (Chemistry Research Department, Nuclear Science Research School, Nuclear Science and Technology Research Institute)
Salavati-Niasari, Masoud (Department of Chemistry, Kashan University)
Publication Information
Bulletin of the Korean Chemical Society / v.29, no.1, 2008 , pp. 94-98 More about this Journal
Abstract
A fundamental study was developed concerning the novel solvent extraction of the tetravalent metal ions; zirconium(IV), hafnium(IV) and thorium(IV). Their extraction behavior in toluene was investigated with a recently synthesized naphthol-derivative Schiff base, 1-({[4-(4-{[(E)-1-(2-hydroxy-1-naphthyl)methyliden]amino}phenoxy) phenyl]imino}methyl)-2-naphthol (HAPMN). The spectrophotometrical examination of the complex formation between HAPMN and the Zr(IV), Hf(IV) and Th(IV) ions in acetonitrile revealed the formation of stable 1:1 complexes in the solution. After the thorium extraction in toluene, it was found that [Th(OH)3HA] was the respective deriving substance. While, in the case of zirconium and hafnium extraction, the extracted adduct was found to be [M4(OH)8(H2O)16Cl62HA]. The stoichiometric coefficients of these extracted species were determined by the slope analysis method. The extraction reaction followed a cation exchange mechanism.
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1 Spinu, C.; Kriza, A. Acta Chim. Slov. 2000, 47, 179
2 Benabdallah, T.; Al-Taiar, A. H.; Reffas, H. S. Afr. J. Chem. 2004, 57, 33
3 Ohashi, Y. Bull. Chem. Soc. Jpn. 1997, 70, 1319   DOI   ScienceOn
4 Yaftian, M. R.; Hassanzadeh, L.; Eshraghi, M. E.; Matt, D. Sep. Purif. Technol. 2003, 31, 261   DOI   ScienceOn
5 Schiff, H. Ann. Suppl. 1864, 3, 343
6 Yoon, T. P.; Jacobsen, E. N. Science 2003, 299, 1691   DOI   ScienceOn
7 Rihter, B.; Srittari, S.; Hunter, S.; Masnovi, J. J. Am. Chem. Soc. 1993, 115, 3918   DOI   ScienceOn
8 Cimmeman, Z.; Galic, N.; Bosner, B. Anal. Chim. Acta 1997, 343, 145   DOI   ScienceOn
9 Welcher, F. J. The Analytical Uses of Ethylenediamine Tetra Acetic Acid; D. VanNostrand Company, Inc.: Princeton, New Jersey, New York, 1957; p 185
10 Rydberg, J.; Cox, M.; Musikas, C.; Choppin, C. R. Solvent Extraction Principle and Practice; Marcel Dekker, Inc.: New York, 2004
11 Caletka, R. The Chemistry of Aqueous Solution of Zirconium, Chemicke Listy 1964, 58, 349
12 Biswas, R. K.; Hayat, M. A. Hydrometallurgy 2002, 63, 149   DOI   ScienceOn
13 Biswas, R. K.; Hayat, M. A. Hydrometallurgy 2004, 75, 45   DOI   ScienceOn
14 Solovkin, A. S.; Tsvetkova, S. V. Russ. Chem. Rev. 1962, 31, 655   DOI   ScienceOn
15 Baes, C. F.; Meyer, N. J.; Roberts, C. E. Inorg. Chem. 1965, 4, 518   DOI
16 Arnaud-Neu, F.; Browne, J. K.; Byrne, D.; Marrs, D. J.; Mckervey, M. A.; O'Hagan, P.; Schwing-Weill, M. J.; Walker, A. Chem. Eur. J. 1999, 5, 175   DOI   ScienceOn
17 Hentz, F. C.; Tyree, S. Y. Inorg. Chem. 1965, 4, 873   DOI
18 Malone, J. F.; Marrs, D. J.; McKervey, M. A.; O'Hagan, P.; Thompson, N.; Walker, A.; Arnaud-Neu, F.; Mauprivez, O.; Schwing-Weill, M. J.; Dozol, J. F.; Roquette, H.; Simon, N. J. Chem. Soc. Chem. Commun. 1995, 2151
19 Arnaud-Neu, F.; Bohmer, V.; Dozol, J. F.; Gruttner, C.; Jakobi, R. A.; Kraft, D.; Mauprivez, O.; Roquette, H.; Schwing-Weill, M. J.; Simon, N.; Vogt, W. J. Chem. Soc. Perkin Trans. 1996, 2, 1175
20 Yaftian, M. R.; Taheri, R.; Matt, D. Phosphorus Sulfur Silicon 2003, 178, 1225   DOI   ScienceOn
21 CRC Handbook of Chemistry and Physics, 87th ed.; 2006
22 Lee, J. D. Concise Inorganic Chemistry, 5th ed.; Chapman & Hall: London, 1996; p 684
23 Choppin, G. R.; Khankhasayev, M. K. H. Chemical Separation Technologies and Related Methods of Nuclear Waste Management; Kluwer: Dordrecht, 1999
24 Horwitz, E. P.; Chiarizia, R. In Separation Techniques in Nuclear Waste Management; Chipmen, N. A.; Wai, C. M., Eds.; CRC Press: Boca Raton, FL, 1996
25 White, D. J.; Laing, N.; Miller, H.; Parsons, S.; Colesb, S.; Tasker, P. A. Chem. Commun. 1999, 2077
26 Mohammadhosseinia, M.; Tehrani, M. S. J. Chin. Chem. Soc. 2006, 53, 1119   DOI
27 Ganjali, M. R.; Pourjavid, M. R.; Babaei, L. H. Quim. Nova 2004, 27, 213   DOI   ScienceOn
28 Shamsipur, M.; Ghiasvand, A. R.; Sharghi, H.; Naeimi, H. Anal. Chim. Acta 2000, 408, 271   DOI   ScienceOn
29 Ganjali, M. R.; Poursaberi, T.; Babaei, L. H.; Rouhani, S.; Yousefi, M.; Kargar-Razi, M.; Moghimi, A.; Aghabozorg, H.; Shamsipur, M. Anal. Chim. Acta 2001, 440, 81   DOI   ScienceOn
30 Rouhollahi, A.; Zolfonoun, E.; Niasari, M. S. Sep. Purif. Technol. 2007, 54, 28   DOI   ScienceOn
31 Shamsipur, M.; Yousefi, M.; Hoseini, M.; Ganjali, M. R.; Sharghi, H.; Naeimi, H. Anal. Chem. 2001, 73, 2869   DOI   ScienceOn
32 Shamsipur, M.; Saeidi, M.; Yari, A.; Yaganeh-Faal, A.; Mashhadizadeh, M. H.; Azimi, G.; Naeimi, H.; Sharghi, H. Bull. Korean Chem. Soc. 2004, 25, 629   DOI   ScienceOn
33 Cozzi, P. G. Chem. Soc. Rev. 2004, 33, 410   DOI   ScienceOn
34 Zhang, W.; Loehach, J. L.; Wilson, S. R.; Jacobsen, E. N. J. Am. Chem. Soc. 1990, 112, 2801   DOI
35 Fry, A. J.; Fry, P. F. J. Org. Chem. 1993, 58, 3496   DOI   ScienceOn
36 Oshima, S.; Hirayama, N.; Kubono, K.; Kokusen, H.; Honjo, T. Anal. Sci. 2002, 18, 1351   DOI   ScienceOn
37 Ghasemi, J.; Shamsipur, M. J. Coord. Chem. 1995, 36, 183   DOI   ScienceOn
38 Sadeeek, S. A.; Refat, M. S.; Teleb, S. M. Bull. Chem. Soc. Ethiop. 2004, 18, 149
39 Panda, C. R.; Chakravortty, V.; Dash, C. K. J. Radioanal. Nucl. Chem. 1987, 108, 65   DOI
40 Singhal, A.; Toth, L. M.; Lin, J. S.; Affhofter, K. J. Am. Chem. Soc. 1996, 118, 11529   DOI   ScienceOn
41 Lima, L. F.; Corraza, M. L.; Cardozo-Filho, L.; Márquez-Alvarez, H.; Antunes Braz, O. A. C. J. Chem. Engin. 2006, 23, 83