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http://dx.doi.org/10.5012/bkcs.2008.29.1.148

Lithium Chloride-Imidazolium Chloride Melts for the Coupling Reactions of Propylene Oxide and CO2  

Nguyen, Ly Vinh (Department of Chemistry and Research Institute of Basic Sciences, Kyung Hee University)
Lee, Bo-Ra (Department of Chemistry and Research Institute of Basic Sciences, Kyung Hee University)
Nguyen, Dinh Quan (Environment and Process Division, Korea Institute of Science and Technology)
Kang, Min-Jung (Bioanalysis & Biotransformation Center, Korea Institute of Science and Technology)
Lee, Hyun-Joo (Environment and Process Division, Korea Institute of Science and Technology)
Ryu, Seol-Ryu (Department of Chemistry and Research Institute of Basic Sciences, Kyung Hee University)
Kim, Hoon-Sik (Department of Chemistry and Research Institute of Basic Sciences, Kyung Hee University)
Lee, Je-Seung (Department of Chemistry and Research Institute of Basic Sciences, Kyung Hee University)
Publication Information
Bulletin of the Korean Chemical Society / v.29, no.1, 2008 , pp. 148-152 More about this Journal
Abstract
A series of lithium chloride-imidazolium chloride (LiCl-[imidazolium]Cl) melts were prepared and their catalytic activities were evaluated for the coupling reactions of propylene oxide and CO2. At the constant mole of LiCl, the catalytic activities of LiCl-[imidazolium]Cl melts increased with increasing molar ratio of [imidazolium]Cl/LiCl up to 2, but thereafter decreased rapidly. The variation of alkyl groups on the imidazolium ring showed a negligible effect on the catalytic activity, but the number of alkyl groups present on the imidazolium cation exerts a pronounced effect. Catalysis and electrospray ionization tandem mass spectral analysis results of LiCl-[imidazolium]Cl melts imply that the activity of the melt is strongly related to the amount of LiCl2- generated from the melt.
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