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http://dx.doi.org/10.5012/bkcs.2007.28.8.1346

A Kinetic Consideration on the Selective Adsorption and Molecular Recognition by Molecularly Imprinted Polymer  

Li, Wuke (Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University)
Li, Songjun (Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University)
Luo, Gang (Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University)
Ding, Kerong (Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University)
Publication Information
Bulletin of the Korean Chemical Society / v.28, no.8, 2007 , pp. 1346-1352 More about this Journal
Abstract
This article presents an original work on kinetically studying the selective adsorption and recognition by molecularly imprinted polymer (MIP). With S-naproxen as template, the imprinted polymer was prepared. The result indicates that the prepared polymer shows a more complicated sorption toward S-naproxen than toward its enantiomer R-naproxen. The rate constant in the case of template appears to be a variable. There are also significant deviations from the idealized Langmuir model. Related information indicates that these, in logic, can be a result of biomimic structural and functional complements between imprint and the template, which makes the polymer capable of selectively recognizing the imprint species.
Keywords
Molecularly imprinted polymer; Adsorption; Kinetics;
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