Browse > Article
http://dx.doi.org/10.5012/bkcs.2007.28.12.2315

Determination of Epinephrine Using Sodium Iodate in Chemiluminescence  

Lee, J.S. (Department of Chemistry, NSBT, Dankook University)
Lim, H.B. (Department of Chemistry, NSBT, Dankook University)
Publication Information
Bulletin of the Korean Chemical Society / v.28, no.12, 2007 , pp. 2315-2318 More about this Journal
Abstract
Epinephrine was determined using a lab-made chemiluminescence (CL) system with air pump. Luminolsodium IO4? chemiluminescence system was employed to produce the luminescence of epinephrine. In the reaction, epinephrine was oxidized to produce superoxide or singlet oxygen by periodate in alkaline solution, which enhanced CL of luminol. For optimization, various buffers, such as phosphate, borate, and tris, were studied in this experiment. Compared to NaOH, the phosphate and borate buffer showed better reproducibility with similar sensitivity. Small amount of sample, 22 μL, was required for a measurement. The limit of quantification for epinephrine was obtained to be ~10?9 g/mL after optimization.
Keywords
Chemiluminescence; Epinephrine; Luminol; Sodium iodate;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
Times Cited By Web Of Science : 1  (Related Records In Web of Science)
Times Cited By SCOPUS : 1
연도 인용수 순위
1 Atta, N. F.; Galal, A.; Karagozler, A. E.; Russell, G. C.; Zimmer, H.; Mark, H. B. Biosens. Bioelectron. 1991, 6, 333   DOI   ScienceOn
2 Zhu, R.; Kok, W. T. Anal. Chem. 1997, 69, 4010   DOI   ScienceOn
3 Hsuch, C. C.; Liu, Y.; Henry, M.; Freund, M. S. Anal. Chim. Acta 1999, 397, 135   DOI   ScienceOn
4 Van der Hoorn, F. A. J.; Boomsma, F.; Man in 't Veld, A. J.; Schalekamp, M. A. D. H. J. Chromatogr. 1989, 487, 17   DOI   ScienceOn
5 Zhou, G. J.; Zhang, G. F.; Chen, H. Y. Anal. Chim. Acta 2002, 463, 257   DOI   ScienceOn
6 Sun, X.; Gillis, K. D. Anal. Chem. 2006, 78, 2521   DOI   ScienceOn
7 Nalewajko, E.; Wiszowata, A.; Kojlo, A. J. of Pharm. and Biomed. Anal. 2007, 43(5), 1673   DOI   ScienceOn
8 Lisdat, F.; Wollenberger, U.; Makower, A.; Hortnagl, H.; Pfeiffer, D.; Scheller, F. W. Biosens. Bioelectron. 1997, 12, 1199   DOI   ScienceOn
9 Riggin, R. M.; Kissinger, P. T. Anal. Chem. 1977, 49, 2109   DOI   ScienceOn
10 Hallman, H.; Farnebo, L. D.; Hamberger, B.; Jonson, G. Life Sci. 1978, 23, 1049   DOI   ScienceOn
11 Szeponik, J.; Moeller, B.; Pfeiffer, D.; Lisdat, F.; Wollenberger, U.; Makower, A.; Scheller, F. W. Biosens. Bioelectron. 1997, 12, 947   DOI   ScienceOn
12 Mitsui, A.; Nohta, H.; Ohkura, Y. J. Chromatogr. 1985, 344, 61   DOI   ScienceOn
13 Cao, L. Biomedical Chromatography: BMC 2007, 21(7), 708   DOI   ScienceOn
14 Zhou, L.; Wang, S.; Tian, K.; Dong, Y.; Hu, Z. J. of Sep. Sci. 2007, 30(1), 110   DOI   ScienceOn
15 Thomas, A.; Geyer, H.; Mester, H. J.; Schanzer, W.; Zimmermann, E.; Thevis, M. Chromatographia 2006, 64(9/10), 587   DOI   ScienceOn
16 Carrera, V.; Sabater, E.; Vilanova, E.; Sogorb, M. A. J. of Chromatogr. B 2007, 847(2), 88   DOI   ScienceOn
17 Nakagama, T.; Yamada, M.; Suzuki, S. Anal. Chim. Acta 1989, 217, 371   DOI   ScienceOn
18 Hong, H.; Lim, H. B. Bull. Korean Chem. Soc. 2005, 26(12), 1937   DOI   ScienceOn
19 Takezawa, K.; Tsunoda, M.; Murayama, K.; Santa, T.; Imai, K. Analyst 2000, 125, 293   DOI   ScienceOn
20 Deftereos, N. T.; Calokerinos, A. C.; Efstathiou, C. E. Analyst 1993, 118, 627   DOI   ScienceOn
21 Hong, H.; Lim, H. B. Anal. Sciences 2006, 22, 613   DOI   ScienceOn
22 Liu, Y. M.; Wang, C. Q.; Mu, H. B.; Cao, J. T.; Zheng, Y. L. Electrophoresis 2007, 28(12), 1937   DOI   ScienceOn
23 Cans, A. S.; Wittenberg, N.; Eves, D.; Karlsson, R.; Karlsson, A.; Orwar, O.; Ewing, A. Anal. Chem. 2003, 75, 4168   DOI   ScienceOn
24 Ciolkowski, E. L.; Cooper, B. R.; Jankowski, J. A.; Jorgenson, J. W.; Wightman, R. M. J. Am. Chem. Soc. 1992, 114, 2815   DOI
25 Yao, H.; Sun, Y. Y.; Lin, X.; Cheng, J.; Huang, L. Luminescence 2006, 21(2), 112   DOI   ScienceOn
26 Paleologos, E. K.; Vlessidis, A. G.; Karayannis, M. I.; Evmiridis, N. P. Anal. Chim. Acta 2003, 477, 223   DOI   ScienceOn
27 Chen, T. K.; Luo, G.; Ewing, A. G. Anal. Chem. 1994, 66, 3031   DOI   ScienceOn
28 Tsunodaa, M.; Uchinoa, E.; Imaib, K.; Hayakawac, K.; Funatsua, T. J. of Chromatogr. A 2007, 1164(1/2), 162   DOI   ScienceOn
29 Chow, R. H.; von Ruden, L.; Neher, E. Nature 1992, 356, 60   DOI   ScienceOn