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http://dx.doi.org/10.5012/bkcs.2007.28.12.2253

Polarity Probing Two-Photon Fluorophores Based on [2.2]Paracyclophane  

Woo, Han-Young (Department of Nanomaterials Engineering (BK21), Pusan National University)
Korystov, Dmitry (Institute for Polymers and Organic Solids, University of California)
Jin, Young-Eup (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University)
Suh, Hong-Suk (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University)
Publication Information
Bulletin of the Korean Chemical Society / v.28, no.12, 2007 , pp. 2253-2260 More about this Journal
Abstract
A series of tetra donor substituted [2.2]paracyclophane-based two-photon absorption (TPA) fluorophores were synthesized in neutral and cationic forms. The imaging activity of overall set of fluorophores was studied by the two-photon induced fluorescence (TPIF) method in a range of solvents. We also measured a clear progression toward a longer photoluminescence lifetime with increasing solvent polarity (intrinsic photoluminescence lifetime, τi: ~2 ns in toluene → 12-16 ns in water). The paracyclophane fluorophores with this unique property can be utilized as an optical polarity probe for the biomolecular substrates. The combined measurement of the two-photon fluorescence microscopy (TPM) cell image and TPIF lifetime can give us a better understanding of the biological processes and local environments in the cells.
Keywords
Two-photon absorption; Bioimaging; Two-photon fluorophore; Paracyclophane; Fluorescent label;
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