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http://dx.doi.org/10.5012/bkcs.2007.28.11.1985

Analysis of Heavy Metal Toxic Ions by Adsorption onto Amino-functionalized Ordered Mesoporous Silica  

Showkat, Ali Md (Department of Chemistry Graduate School, Kyungpook National University)
Zhang, Yu-Ping (Henan Institute of Science and Technology)
Kim, Min-Seok (Department of Chemistry Graduate School, Kyungpook National University)
Gopalan, Anantha Iyengar (Department of Chemistry Graduate School, Kyungpook National University)
Reddy, Kakarla Raghava (Department of Chemistry Graduate School, Kyungpook National University)
Lee, Kwang-Pill (Department of Chemistry Graduate School, Kyungpook National University)
Publication Information
Bulletin of the Korean Chemical Society / v.28, no.11, 2007 , pp. 1985-1992 More about this Journal
Abstract
Ordered mesoporous silica (MCM-41) materials with different textural properties were prepared using alkyl (dodecyl, cetyl, eicosane) trimethyl ammonium bromide (DTAB, CTAB, ETAB, respectively) as structure directing surfactants, functionalized with amine groups and used as adsorbent for the toxic metal ions, Cr (VI), As (V), Pb (II) and Hg (II). Amino functionalization of mesoporous MCM-41 was achieved by cocondensation of N-[3-(trimethoxysilyl)-propyl] aniline with tetraethyl orthosilicate. Adsorption isotherm and adsorption capacity of the amine functionalized materials for Cr (VI), As (V), Pb (II) and Hg (II) ions were followed by inductively coupled plasma mass spectrometry (ICP-MS). Results demonstrate that amine functionalized MCM-41 prepared with ETAB showed higher adsorption capacity for Cr (VI), As (V), Pb (II) and Hg (II) ions in comparison to MCM-41 prepared with CTAB and DTAB. The higher adsorption capacity for MCM-41(ETAB) was correlated with amine content in the material (determined by CHN analysis) and relative decrease in pore volume and pore diameter. X-ray diffraction (XRD) analysis, nitrogen adsorptiondesorption measurements and Fourier Transform infrared spectrometry (FTIR) were used to follow the changes in the textural parameters and surface properties of the mesoporous materials as a result of amine functionalization to correlate with the adsorption characteristics. The adsorption process was found to depend on the pH of the medium.
Keywords
Mesoporous; Textural parameters; Adsorbent; Heavy metal ions; MCM-41;
Citations & Related Records
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1 Autochshuk, V.; Jaroniec, M. Chem. Mater. 2000, 12, 2496   DOI   ScienceOn
2 Zhao, X. S.; Lu, G. Q.; Whittaker, A. J.; Millar, G. J.; Zhu, H. Y. J. Phys. Chem. B 1997, 101, 6525   DOI   ScienceOn
3 Diaz, J. F.; Balkus, K. J.; Bedioui, F.; Kurshev, V.; Kevan, L. Chem. Mater. 1997, 9, 61   DOI   ScienceOn
4 Cho, S.-Y.; Kim, N.-R.; Cao, G.; Kim, J.-G.; Chung, C.-M. Bull. Kor. Chem. Soc. 2006, 27(3), 403   DOI   ScienceOn
5 Kresge, C. T.; Leonowicz, M. E.; Roth, W. J.; Vartuli, J. C.; Beck, J. S. Nature 1992, 359, 710   DOI
6 Beck, J. S.; Vartuli, J. C.; Roth, W. J.; Leonowicz, M. E.; Kresge, C. T.; Schmitt, K. D.; Chu, C. T.-W.; Olson, D. H.; Sheppard, E. W.; McCullen, S. B.; Higgins, J. B.; Schlenker, J. L. J. Am. Chem. Soc. 1992, 114, 10834
7 Raman, N. K.; Anderson, M. T.; Brinker, C. J. Chem. Mater. 1996, 8, 1682   DOI   ScienceOn
8 Sayari, A.; Liu, P. Micropor. Mesopor. Mater. 1997, 12, 149   DOI   ScienceOn
9 Ciesla, U.; Schuth, F. Micropor. Mesopor. Mater. 1999, 27, 131   DOI   ScienceOn
10 Selvam, P.; Bhatia, S. K.; Sonwane, C. G. Ind. Eng. Chem. Res. 2001, 40, 3237   DOI   ScienceOn
11 Bae, J. Y.; Choi, S.-H.; Bae, B.-S. Bull. Kor. Chem. Soc. 2006, 27(10), 1562   DOI   ScienceOn
12 Huo, Q.; Margolese, D.; Stucky, G. D. Chem. Mater. 1996, 8, 1147   DOI   ScienceOn
13 Kruk, M.; Jaroniec, M.; Sakamoto, Y.; Terasaki, O.; Ryoo, R.; Ko, C. H. J. Phys. Chem. B 2000, 104, 292   DOI   ScienceOn
14 Lee, K.-P.; Showkat, A. M.; Gopalan, A.; Kim, S.-H.; Choi, S.-H. Macromolecules 2005, 38, 364   DOI   ScienceOn
15 Showkat, A. M.; Lee, K.-P.; Gopalan, A.; Kim, S.-H.; Choi, S.-H. Polymer 2005, 46, 1804   DOI   ScienceOn
16 Moller, K.; Bein, T. Chem. Mater. 1998, 10, 2950   DOI   ScienceOn
17 Brunel, D. Micropor. Mesopor. Mater. 1999, 27, 329   DOI   ScienceOn
18 Feng, X.; Fryxell, G. E.; Wang, L.-Q.; Kim, A. Y.; Liu, J.; Kemner, K. M. Science 1997, 276, 923
19 Liu, J.; Feng, X.; Fryxell, G. E.; Wang, L.-Q.; Kim, A. Y.; Gong, M. Adv. Mater. 1998, 10, 161
20 Kawi, S. Chem. Commun. 1998, 13, 1407
21 Shen, S. C.; Kawi, S. J. Phys. Chem. B 1999, 103, 8870   DOI   ScienceOn
22 Liu, A. M.; Hidajat, K.; Kawi, S.; Zhao, D. Y. Chem. Commun. 2000, 13, 1145
23 Brunel, D. Micropor. Mesopor. Mater. 1999, 27, 329   DOI   ScienceOn
24 Ehlers, L. J.; Pfeffe, M. J.; Melia, C. R. O. Environ. Sci. Technol. 2001, 34, 464   DOI   ScienceOn
25 Heary, L.; Ray, D. Environ. Sci. Technol. 1987, 21, 1187   DOI   ScienceOn
26 Baes, C. F.; Mesmer, Jr, R. E. The Hydrolysis of Cations; John Wiley and Sons: New York, U.S.A., 1976
27 Roundhill, D. M.; Koch, H. F. Chem. Soc. Rev. 2002, 31, 60   DOI   ScienceOn
28 Harper, T. R.; Kingham, N. W. Water Environ. Res. 1992, 64, 200   DOI
29 Fox, K. R.; Sorg, T. J. J. Am. Water Works Assoc. 1987, 79, 81
30 De Carlo, E. H.; Thomas, D. M. Environ. Sci. Technol. 1985, 19, 538
31 Min, J.; Eun, S. W.; Jae, K. P.; Sang, C. Environ. Sci. Technol. 2003, 37, 5062   DOI   ScienceOn
32 Toshiyuki, Y.; Takashi, T.; Hideaki, Y. J. Colloid Interface Sci. 2004, 274, 451   DOI   ScienceOn
33 Faust, S. D.; Ali, O. M. Chemistry of Water Treatment; Butterworth: Boston, U.S.A., 1983
34 Wittbrodt, P. R.; Palmer, C. D. Environ. Sci. Technol. 1995, 29, 255   DOI   ScienceOn
35 Sterrns, D. M.; Kennedy, L. J.; Courtney, K. D.; Giangrande, P. H.; Phieffer, L. S.; Wetterhahn, K. E. Biochemistry 1995, 34, 910   DOI   ScienceOn
36 Mohan, D.; Guputa, V. K.; Srivastava, S. K.; Chander, S. Colloids Surf. A 2001, 177, 169   DOI   ScienceOn
37 Barton, T. J.; Bull, L. M.; Klemperer, W. G.; Loy, D. A.; McEnaney, B.; Misono, M.; Monson, P. A.; Scherer, G. W.; Vartuli, J. C.; Yaghi, O. M. Chem. Mater. 1999, 11, 2633   DOI   ScienceOn
38 Feng, X.; Fryxell, E.; Wang, L.-Q.; Kim, Y.; Liu, J.; Kemner, K. M. Science 1997, 276, 923
39 Mercier, L.; Pinnavaia, T. J. Environ. Sci. Technol. 1998, 32, 2749   DOI   ScienceOn
40 Liu, A. M.; Hidajat, K.; Kawi, S.; Zhao, D. Y. Chem. Commun. 2000, 1145
41 Zhang, L. Z.; Cheng, P.; Liao, D.-Z. J. Chem. Phys. 2002, 117, 5959
42 Wei, Z.; Zhang, Z.; Wan, M. Langmuir 2002, 18, 917   DOI   ScienceOn
43 Ryoo, R.; Kim, J. K. J. Chem. Soc. Chem. Commun. 1995, 711
44 Ryoo, R.; Jun, S. J. Phys. Chem. B 1997, 101, 317   DOI   ScienceOn
45 Ryoo, R.; Ko, C. H.; Park, I. S. Chem. Commun. 1999, 1413
46 Mercier, L.; Pinnavaia, T. J. Environ. Sci. Technol. 1998, 32, 2749   DOI   ScienceOn
47 Mercier, L.; Pinnavaia, T. J. Micropor. Mesopor. Mater. 1998, 20, 101   DOI   ScienceOn
48 Celis, R.; Hermosin, M. C.; Cornejo, J. Environ. Sci. Technol. 2000, 34, 4593   DOI   ScienceOn
49 Zhao, X. S.; Lu, G. Q. J. Phys. Chem. B 1998, 102, 1556   DOI   ScienceOn
50 Chen, S.-L.; Dzeng, S. R.; Yang, M.-H.; Chlu, K.-H.; Shleh, G. M.; Wal, C. M. Environ. Sci. Technol. 1994, 28, 877
51 Nickson, R.; McArthur, J.; Burgess, W.; Ahmed, K. M.; Ravenscroft, P.; Rahman, M. Nature 1998, 395, 338   DOI   ScienceOn
52 Fryxell, G. E.; Liu, J.; Hauser, T. A.; Nie, Z.; Ferris, K. F.; Mattigod, S.; Gong, M.; Hallen, R. T. Chem. Mater. 1999, 11, 2148   DOI   ScienceOn
53 Yoshitake, H.; Yokoi, T.; Tatsumi, T. Chem. Mater. 2002, 14, 4603   DOI   ScienceOn
54 Hongshao, Z.; Stanforth, R. Environ. Sci. Technol. 2001, 35, 4753   DOI   ScienceOn
55 Water. Polu. Conf. Fed. 1978, 50, 993
56 Navarro, R. R.; Sumi, K.; Matumura, M. Water Res. 1999, 33, 2037   DOI   ScienceOn
57 Huang, C. P.; Hao, O. J. J. Environ. Technol. Lett. 1989, 10, 863   DOI   ScienceOn
58 Zamzow, M. J.; Eichbaum, B. R.; Sandgren, K. R.; Shanks, D. E. Separ. Sci. Technol. 1990, 25, 1555   DOI