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http://dx.doi.org/10.5012/bkcs.2006.27.8.1171

Coupling Reaction of CO2 with Epoxides by Binary Catalytic System of Lewis Acids and Onium Salts  

Bok, Taekki (Department of Molecular Science and Technology, Ajou University)
Noh, Eun Kyung (Department of Molecular Science and Technology, Ajou University)
Lee, Bun Yeoul (Department of Molecular Science and Technology, Ajou University)
Publication Information
Bulletin of the Korean Chemical Society / v.27, no.8, 2006 , pp. 1171-1174 More about this Journal
Abstract
Various off-the-shelf Lewis acids in conjunction with various onium salts are screened for coupling reaction of $CO_2$ with epoxides. Among the tested ones, $VCl_3/n-Bu_4NOAc$, $VCl_3/(n-Bu_4NCl$ or PPNCl), $FeCl_3/ n-Bu_4NOAc$, and $FeCl_3/ n-Bu_4NOAc$are proved to be highly active. Propylene oxide, epichlorohydrin, styrene oxide, and cyclohexene oxide can be converted over 90% yields to the corresponding cyclic carbonates without the use of organic solvents under mild conditions by 0.1-1.0 mol% catalyst charge.
Keywords
Cyclic carbonatel; Carbon dioxide; Epoxide; Coupling reaction;
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