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http://dx.doi.org/10.5012/bkcs.2006.27.8.1127

Determination of Salicylate by Selective Poly(vinylchloride) Membrane Electrode Based on N,N'-1,4-Butylene Bis(3-methyl salicylidene iminato) Copper(II)  

Mazloum Ardakani, M. (Department of Chemistry, Faculty of Science, Yazd University)
Jamshidpoor, M. (Department of Chemistry, Faculty of Science, Kashan University)
Naeimi, H. (Department of Chemistry, Faculty of Science, Kashan University)
Heidarnezhad, A. (Department of Chemistry, Faculty of Science, Kashan University)
Publication Information
Bulletin of the Korean Chemical Society / v.27, no.8, 2006 , pp. 1127-1132 More about this Journal
Abstract
A new salicylate-selective electrode based on the complex N,N'-1,4-butylene bis(3-methyl salicylidene iminato) copper(II) as the membrane carrier was developed. The electrode exhibits a good Nernstian slope of 59.1 ${\pm}$ 1.0 mV/decade and a linear range of $1.0\;{\times}\;10^{-6}$-1.0 M for salicylate. The limit of detection was $5.0\;{\times}\;10^{-7}$ M. It has a fast response time 10 s and can be used for more than three months. The selective coefficients were determined by the fixed interference method (FIM) and could be used in the pH range 4.5-10.5. It was employed as an indicator electrode for direct determination of salicylate in pharmaceutical samples.
Keywords
Salicylate; Salicylate-selective electrode; Potentiometry; Ionophore;
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1 Thomas, J. G. R.; Moody, G. J.; Oke, R. B. Analyst 1970, 95, 910   DOI
2 Bakker, E.; Buhlmann, P.; Pretsch, E. Chem. Rev. 1997, 97, 3083   DOI   ScienceOn
3 Arnold, M. A.; Solsky, R. L. Anal. Chem. 1986, 58, 84R   DOI
4 Wotring, V. J.; Johnson, D. M.; Bachas, L. G. Anal. Chem. 1990, 62, 1506   DOI
5 Hutchins, R. S.; Bachas, L. G. Anal. Chem. 1995, 67, 1654   DOI   ScienceOn
6 Aslan (Yilmaz), N.; Kenar, A.; Atakol, O.; Kilic, E. Anal. Sci. 2001, 17, 1269   DOI   ScienceOn
7 Mazloum, M.; Ensafi, A. A.; Salavati, M.; Mirhoseini, S. Anal. Chim. Acta 2002, 462, 25   DOI   ScienceOn
8 Sharghi, H.; Naeimi, H. Iran J. Chem. & Chem. Eng. 1999, 18, 72
9 Huser, M.; Gehrig, P. M.; Morf, W. E.; Simon, W.; Lindner, C.; Jeney, J.; Toth, K.; Pungor, E. Anal. Chem. 1991, 63, 1380   DOI
10 Morf, W. E.; Khar, G.; Simon, W. Anal. Lett. 1974, 719
11 Amini, M. K.; Shahrokhian, S.; Tangestaninejad, S. Anal. Chim. Acta 1999, 402, 137   DOI   ScienceOn
12 Nomura, S. Analyst 1995, 120, 1503
13 Amini, M. K.; Shahrokhian, S. Anal. Chem. 1999, 71, 2502   DOI   ScienceOn
14 Wegmann, D.; Weiss, H.; Ammann, D.; Morf, W. E.; Pretsch, E.; Sagahara, K.; Simon, W. Mikrochim. Acta 1984, III(1-2), 1
15 Schaller, U.; Bakker, E.; Spichiger, U. E.; Pretsch, E. Anal. Chem. 1994, 66, 391   DOI   ScienceOn
16 IUPAC Pure Appl. Chem. 1976, 48, 27
17 Buck, R. P. Anal. Chem. 1972, 44, 270R   DOI   ScienceOn
18 Daunert, S.; Wallace, S.; Florido, A.; Bachas, L. G. Anal. Chem. 1991, 63, 1676   DOI
19 Leyzerovich, N. N.; Shvedene, N. V.; Bilkova, Y. N.; Tomilova, L. G.; Pletnev, I. V. Electroanalysis 2001, 3, 246
20 Hauser, P. C. Anal. Chim. Acta 1993, 278, 227   DOI   ScienceOn
21 Hassan, S. S.; Hamada, M. M. A. Analyst 1988, 113, 1709   DOI
22 Hisamoto, H.; Siswanta, D.; Nishihara, H.; Suzuki, K. Anal. Chim. Acta 1995, 304, 171   DOI   ScienceOn
23 Chang, Q.; Meyerhoff, M. E. Anal. Chim. Acta 1986, 186, 81   DOI   ScienceOn
24 Katsu, T.; Mori, Y. Talanta 1996, 43, 755   DOI   ScienceOn
25 Shahrokhian, S.; Amini, M. K.; Kia, R.; Tangestaninejad, S. Anal. Chem. 2000, 72, 956   DOI   ScienceOn
26 Li, Z. Q.; Song, X. P.; Shen, G. L.; Yu, R. Q. Anal. Lett. 1998, 31, 1473   DOI   ScienceOn
27 Chaniotakis, N. A.; Park, S. B.; Meyerhoff, M. E. Anal. Chem. 1989, 61, 566   DOI   ScienceOn
28 Mazloum Ardakany, M.; Ensafi, A. A.; Naeimi, H.; Dastanpoor, A.; Shamelli, A. Russ. J. Electrochem. 2003, 39, 269   DOI
29 Hutchins, R. S.; Bansal, P.; Molina, P.; Alajarin, M.; Vidal, A.; Bachas, L. G. Anal. Chem. 1997, 69, 1273   DOI   ScienceOn
30 Shahrokhian, S.; Hamzehloei, A.; Bagherzadeh, M. Anal. Chem. 2002, 74, 3312   DOI   ScienceOn
31 Firooz, A. R.; Amini, M. K.; Tangestaninejad, S.; Shahrokhian, S. Anal. Lett. 2001, 34, 661   DOI   ScienceOn
32 Xu, L.; Yuan, R.; Zifu, Y.; Qinchai, Y. Anal. Sci. 2005, 21, 287   DOI   ScienceOn
33 British Pharmacopoeia; University Press: Cambridge, 1993; Vol.II
34 Reimann, A. N. Engl. J. Med. 1988, 318, 245   DOI   ScienceOn
35 Kamata, S.; Bhal, A.; Fakunaga, Y.; Marata, A. Anal. Chem. 1998, 60, 2464   DOI   ScienceOn
36 Bakker, E.; Malinowska, E.; Schiller, R. D.; Meyerhoff, M. E. Talanta 1994, 41, 881   DOI   ScienceOn