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http://dx.doi.org/10.5012/bkcs.2006.27.4.539

Proton Transfer Reactions and Ion-Molecule Reactions of Ionized XCH2CH2Y (X and Y = OH or NH2)  

Choi, Sung-Seen (Department of Applied Chemistry, Sejong University)
So, Hun-Young (Korea Research Institute of Standards and Science)
Publication Information
Bulletin of the Korean Chemical Society / v.27, no.4, 2006 , pp. 539-544 More about this Journal
Abstract
Proton transfer reactions and ion-molecule reactions of bifunctional ethanes of $H_2NCH_2CH_2NH_2$, $H_2NCH_2CH_2OH$, and $HOCH_2CH_2OH$ were studied using Fourier transform mass spectrometry (FTMS). The rate constants for proton transfer reactions between the fragment ions and neutral molecules were obtained from the temporal variation of the ion abundances. The rate constants were consistent with the heats of reaction. The fastest proton transfer reactions were the reactions of $CH_2N^+$, $CHO^+$, and $CH_3O^+$ for $H_2NCH_2CH_2NH_2$, $H_2NCH_2CH_2OH$, and $HOCH_2CH_2OH$, respectively. The $[M+13]^+$ ion was formed by the ion-molecule reaction between $H_2C=NH_2 ^+$ or $H_2C=OH^+$ and the neutral molecule. The major product ions generated from the ion-molecule reactions between the protonated molecule and neutral molecule were $[2M+H]^+$, $[M+27]^+$, and $[M+15]^+$.
Keywords
Proton transfer reaction; Ion-molecule reaction; Ethylenediamine; Ethanolamine; Ethylene glycol;
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