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http://dx.doi.org/10.5012/bkcs.2006.27.4.503

Rh2(Opiv)4-Catalyzed Reactions of Diazo Compound Derived from Meldrum's Acid and Styrenes. Efficient Synthesis of Cyclopropanes  

Lee, Yong-Rok (School of Chemical Engineering and Technology, College of Engineering, Yeungnam University)
Choi, Jung-Hyun (School of Chemical Engineering and Technology, College of Engineering, Yeungnam University)
Publication Information
Bulletin of the Korean Chemical Society / v.27, no.4, 2006 , pp. 503-507 More about this Journal
Abstract
The rhodium(II)-catalyzed reactions of diazo compound derived from Meldrum's acid with a variety of styrenes have been examined. These reactions provide a rapid route to the preparation of cyclopropanes with a variety of substituents on the benzene ring. The mechanistic pathway for the formation of these products has been also described in terms of a stepwise mechanism.
Keywords
$Rh_2(Opiv)_4$-catalyzed reactions; Diazo compound; Cyclopropanes;
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