Browse > Article
http://dx.doi.org/10.5012/bkcs.2006.27.10.1593

Highly Copper(II)-selective PVC Membrane Based on a Schiff Base Complex of N,N'-Bis-pyridin-2-ylmethylene-naphthalene-1,8-diamine as an Ionophore  

Jeong, Dae-Cheol (Department of Chemistry and Institute of Basic Science, Chonnam National University)
Lee, Hyo-Kyoung (Department of Chemistry and Institute of Basic Science, Chonnam National University)
Jeon, Seung-Won (Department of Chemistry and Institute of Basic Science, Chonnam National University)
Publication Information
Bulletin of the Korean Chemical Society / v.27, no.10, 2006 , pp. 1593-1596 More about this Journal
Abstract
The polymeric membrane electrodes based on N,N'-bis-pyridin-2-ylmethylene-naphthalene-1,8-diamine as an ion carrier were prepared and tested for the copper-ion selective electrode. The membrane has a linear dynamic range between $10^{-6}$ and $10^{-2}$ M with a Nernstian slope of 29.6 mV per decade, and its detection limit was $10^{-5.62}$M. The potentiometric response is independent of the pH range of 3-5. The proposed electrode showed good selectivity and response for $Cu^{2+}$ over a wide variety of other metal ions in pH 4.0 buffer solutions.
Keywords
Polymeric membrane electrode; N,N'-Bis-pyridin-2-ylmethylene-naphthalene-1,8-diamine; Ionophore; Copper-selective electrode;
Citations & Related Records

Times Cited By Web Of Science : 9  (Related Records In Web of Science)
Times Cited By SCOPUS : 8
연도 인용수 순위
1 Florence, T. M.; Lumsden, B. G.; Fardy, J. J. Anal. Chim. Acta 1983, 151, 281   DOI   ScienceOn
2 Ganjali, M. R.; Golmohammadi, M.; Yousefi, M.; Norouzi, P.; Salavati-Niasari, M.; Javanbakht, M. Analytical Sciences 2003, 19, 223   DOI   ScienceOn
3 Bazooka, Z. Analyst 1988, 113, 1893
4 Fleming, C. A.; Trevors, J. T. J. Water Air Soil Pollut. 1989, 14, 143
5 Morrison, G. M. In Handbook on Metal-Ligand Interactions in Biological Fields; Berthon, G., Ed.; Marcel Dekker: New York, 1995; Vol. 1, Chap. 7A
6 Buhlmann, P.; Pretsch, E.; Bakker, E. Chem. Rev. 1988, 1598
7 Alizadeh, N.; Ershad, S.; Naeimi, H.; Sharghi, H.; Shamsipur, M. Fresenius' J. Anal. Chem. 1999, 365, 511   DOI
8 Kamata, S.; Yamasaki, Y.; Higo, M.; Bhale, A.; Fukanaga, Y. Analyst 1988, 113, 45   DOI
9 Kamata, S.; Bhale, A.; Fukanaga, Y.; Murata, H. Anal. Chem. 1988, 60, 2464   DOI   ScienceOn
10 Casabo, J.; Mestres, L.; Escriche, L.; Texidor, F.; Perez-Jimenez, C. Chem. Soc., Dalton Trans. 1991, 1961
11 Kamata, S.; Murata, H.; Kubo, Y.; Bhale, A. Analyst 1989, 114, 1029   DOI
12 Cobber, P. L. H. M.; Gherkin, R. J. M.; Boomer, J. B.; Barged, P.; Vroom, W.; Reinhoudt, D. N. J. Am. Chem. Soc. 1992, 114, 10573
13 Ren, K. Talanta 1988, 113, 1803
14 Jeong, T.; Lee, H. K.; Jeong, D. C.; Jeon, S. Talanta 2005, 65, 543   DOI   ScienceOn
15 Gupta, K. C.; D'Arc, M. J. Sens. Actuators 2000, B62, 171
16 Gupta, K. C.; D'Arc, M. J. Anal. Chim. Acta 2001, 437, 199   DOI   ScienceOn
17 IUPAC Analytical Chemistry Division, Commission on Analytical Nomenclature. Pure Appl. Chem. 1976, 48, 127   DOI
18 Gupta, V. K.; Prasad, R.; Kumar, A. Talanta 2003, 60, 149   DOI   ScienceOn