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http://dx.doi.org/10.5012/bkcs.2005.26.2.265

Mild and Efficient Silylcyanation of Aldehydes Catalyzed by Zirconium Complex  

Kim, Sung-Soo (Department of Chemistry, Inha University)
Lee, Jun-Tae (Department of Chemistry, Inha University)
Song, Dae-Ho (Department of Chemistry, Inha University)
Lee, Ik-Mo (Department of Chemistry, Inha University)
Park, Sun-Young (Department of Chemistry, Inha University)
Publication Information
Bulletin of the Korean Chemical Society / v.26, no.2, 2005 , pp. 265-267 More about this Journal
Abstract
An efficient method of addition of trimethylsilyl cyanide to aldehydes by employing a zirconium complex as the catalyst has been described. A variety of aromatic, aliphatic, cyclic and heterocyclic aldehydes has been converted into corresponding trimethylsilyl ethers in excellent yield within short reaction time.
Keywords
Zirconium complex; Aldehydes; TMSCN; Silylcyanation;
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