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http://dx.doi.org/10.5012/bkcs.2005.26.1.057

The Potentiometric Studies on the Effects of Various Functional Groups in Disiloxane as an Anion-Selective Ionophore  

Jung, Hyo-Jin (Department of Chemistry, Yonsei University)
Lee, Myong-Euy (Department of Chemistry, Yonsei University)
Lim, Chae-Yun (Department of Chemistry, Yonsei University)
Paeng, Ki-Jung (Department of Chemistry, Yonsei University)
Publication Information
Bulletin of the Korean Chemical Society / v.26, no.1, 2005 , pp. 57-62 More about this Journal
Abstract
The potentiometric responses for various anions are investigated with membrane electrode (membrane 1) based on 1,3-diethyl-1,3-dihydroxy-1,3-bis(2-dimethylaminomethyl ferrocenyl) disiloxane. The nitrate ion-selective electrode based on compound 1 gave a good Nernstian response of 58.18 mV per decade for nitrate with the detection limit of −e5.66 of log [NO3−e]. Compound 1 has all those functional groups and the other two compounds have less functional group of ferrocenyl or ferrocenyl and hydroxide, respectively. Even though, potentiometric response to anions was excellent at pH 5, the selectivity pattern for all three membrane electrode based on series of disiloxane is almost like Hofmeister sequence at pH 5. However, the membrane electrode 1-3 exhibited very different response to anions at pH 7. In this pH, NH2 is not protonated and ionophore may act as neutral carrier. Hydrogen bond may enhance the responsibility to hydrogen acceptors and intramolecular electro-active site may increase the permeability of analyte to ionophore in membrane.
Keywords
1,3-Diethyl-1,3-dihydroxy-1,3-bis(2-dimethylaminomethyl ferrocenyl) disiloxane; Anion-selective ionophore; Potentiometric response;
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