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http://dx.doi.org/10.5012/bkcs.2005.26.12.1965

Influence of Jahn-Teller Distortion on the Magnetic Coupling in Oxalato-Bridged Copper(II) Dimers: An Orbital Interpretation of the Superexchange Mechanism  

Kang, Dae-Bok (Department of Chemistry, Kyungsung University)
Publication Information
Bulletin of the Korean Chemical Society / v.26, no.12, 2005 , pp. 1965-1968 More about this Journal
Abstract
Extended H$\ddot{u}$ckel molecular calculations have been used to analyze how the magnitude of exchange coupling is influenced by the structural distortions in a series of dinuclear six-coordinate copper(II) complexes bridged by the planar bis-bidentate oxalate anion. Copper(II) ions have distorted octahedral surroundings, one being axially elongated and the other compressed. The magnetic interaction is strong in the former complexes and very weak in the latter. This is interpreted as resulting from a switching of magnetic spin orbitals due to the structural distortions (bond elongation or compression) of the copper sites.
Keywords
Spin dimer; Superexchange; Magnetic coupling; Extended H$\ddot{u}$ckel;
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1 Julve, M.; Verdaguer, M.; Gleizes, A.; Philoche-Levisalles, M.; Kahn, O. Inorg. Chem. 1984, 23, 3808   DOI
2 Curtis, N. F.; McCormick, I. R. N.: Waters, T. N. J. Chem. Soc., Dalton Trans. 1973, 1537
3 Felthouse, T. R.; Laskowski, E. J.; Hendrickson, D. N. Inorg. Chem. 1977, 16, 1077   DOI
4 Hay, P. J.; Thibeault, J. C.; Hoffmann, R. J. Am. Chem. Soc. 1975, 97, 4884   DOI
5 Julve, M.; Verdaguer, M.; Kahn, O.; Gleizes, A.; Philoche- Levisalles, M. Inorg. Chem. 1983, 22, 368   DOI
6 Castillo, O.; Luque, A.; Lloret, F.; Roman, P. Inorg. Chem. Commun. 2001, 4, 350   DOI   ScienceOn
7 Smekal, Z.; Travnicek, Z.; Lloret, F.; Marek, J. Polyhedron 1999, 18, 2787   DOI   ScienceOn
8 Castillo, O.; Luque, A.; Roman, P.; Lloret, F.; Julve, M. Inorg. Chem. 2001, 40, 5526   DOI   ScienceOn
9 Glerup, J.; Goodson, P. A.; Hodgson, D. J.; Michelsen, K. Inorg. Chem. 1995, 34, 6255   DOI
10 Calatayud, M. L.; Castro, I.; Sletten, J.; Lloret, F.; Julve, M. Inorg. Chim. Acta 2000, 300-302, 846   DOI   ScienceOn
11 Hoffmann, R. J. Chem. Phys. 1963, 39, 1397   DOI
12 Castro, I.; Faus, J.; Julve, M.; Gleizes, A. J. Chem. Soc., Dalton Trans. 1991, 1937
13 Kansikas, J.; Pajunen, A. Acta Crystallogr., Sect. B 1980, 36, 2423   DOI
14 Castro, I.; Faus, J.; Julve, M.; Mollar, M.; Monge, A.; Gutierrez-Puebla, E. Inorg. Chim. Acta 1989, 161, 97   DOI   ScienceOn
15 Castro, I.; Faus, J.; Julve, M.; Munoz, M. C.; Diaz, W.; Solans, X. Inorg. Chim. Acta 1991, 179, 59   DOI   ScienceOn
16 Julve, M.; Faus, J.; Verdaguer, M.; Gleizes, A. J. Am. Chem. Soc. 1984, 106, 8306   DOI
17 Bencini, A.; Fabretti, A. C.; Zanchini, C.; Zannini, P. Inorg. Chem. 1987, 26, 1445   DOI
18 Soto, L.: Garcia, J.; Escriva, E.; Legros, J.-P.; Tuchagues, J.-P.; Dahan, F.: Fuertes, A. Inorg. Chem. 1989, 28, 3378   DOI
19 Tang, J.; Gao, E.; Bu, W.; Liao, D.; Yan, S.; Jiang, Z.; Wang, G. J. Mol. Struct. 2000, 525, 271   DOI   ScienceOn
20 Cano, J.; Alemany, P.; AIvarez, S.; Verdaguer, M.; Ruiz, E. Chem. Eur. J. 1998, 4, 476   DOI   ScienceOn
21 Nonoyama, M.; Nonoyama, K. J. Inorg. Nucl. Chem. 1981, 43, 2567   DOI   ScienceOn
22 Castillo, O.; Luque, A.; Julve, M.; Lloret, F.; Roman, P. Inorg. Chim. Acta 2001, 315, 9   DOI   ScienceOn
23 Curtis, N. F. J. Chem. Soc. A 1968, 1584   DOI
24 Duggan, D. M.; Barefield, E. K.; Hendrickson, D. N. Inorg. Chem. 1973, 12, 985   DOI
25 Nonoyama, K.; Ojima, H.; Ohki, K.; Nonoyama, M. Inorg. Chim. Acta 1980, 41, 155   DOI   ScienceOn
26 Tuero, L. S.; Garcia-Lozano, J.; Monto, E. E.; Borja, M. B.; Dahan, F.; Tuchagues, J.-P.; Legros, J. P. J. Chem. Soc., Dalton Trans. 1991, 2619
27 Castillo, O.; Muga, I.; Luque, A.; Gutierrez-Zorrilla, J. M.; Sertucha, J.; Vitoria, P.; Roman, P. Polyhedron 1999, 18, 1235   DOI   ScienceOn
28 Tuero, L. S.; Garcia-Lozano, J.; Monto, E. E.; Borja, M. B.; Dahun, F.; Tuchagues, J. P.; Legros, J. P. J. Chem. Soc., Dalton Trans. 1991, 2619
29 Vicente, R.; Escuer, A.; Ferretjans, J.; Stoeckli-Evans, H.; Solans, X.; Font-Bardia, M. J. Chem. Soc., Dalton Trans. 1997, 167
30 Ren, J.; Liang, W.; Whangbo, M.-H. Crystal and Electronic Structure Analysis Using CAESAR.; North Carolina State University: Raleigh, NC, 1998
31 Khan, O. Molecular Magnetism; VCH: New York, 1993
32 Cabrero, J.; Amor, N. B.; de Graaf, C.; Illas, F.; Caballol, R. J. Phys. Chem. A 2000, 104, 9983   DOI   ScienceOn
33 Youngme, S.; van Albada, G. A.; Chaichit, N.; Gunnasoot, P.; Kongsaeree, P.; Mutikainen, I.; Roubeau, O.; Reedijk, J.; Turpeinen, U. Inorg. Chim. Acta 2003, 353, 119   DOI   ScienceOn
34 Soto-Tuero, L.; Garcia-Lozano, J.; Escriva-Monto, E. E.; Beneto-Borja, M.; Dahan, F.: Tuchagues, J.-P.; Legros, J.-P. J. Chem. Soc., Dalton Trans. 1991, 2619
35 Zhang, L.; Bu, W.-M.; Yan, S.-P.; Jiang, Z.-H.; Liao, D.-Z.; Wang, G.-L. Polyhedron 2000, 19, 1105   DOI   ScienceOn